2012-12-24_HYDROLOGY - P2011010

• Permit No: P2011010
• IBM Index Class Name: HYDROLOGY
• Doc Date: 12/24/2012
• Doc Name: WATER QUALITY 2012, 4TH QTR
• From: RIO GRANDE SILVER
• To: DRMS
• Type & Sequence: MD2
• Email Name: RCO
• Media Type: D
• Archive: No

ACZ Laboratories, Inc.
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334 -5493
Rio Grande Silver, Inc.
ACZ ID WORKNUM PARAMETER
METHOD QUAL DESCRIPTION
REPAD.15 06 05 01
Nickel (1312)
Potassium (1312)
WG330950 Selenium (1312)
WG330840 Silica (1312)
WG330950 Silver(1312)
WG330840 Sodium (1312)
WG330950 Thallium (1312)
Uranium (1312)
Zinc (1312)
WG330759 Chloride (1312 DI)
Inorganic Extended
Qualifier Report
ACZ Project ID: L96798
RA Relative Percent Difference (RPD) was not used for data
validation because the sample concentration is too low for
accurate evaluation (< 10x MDL)
RA Relative Percent Difference (RPD) was not used for data
validation because the sample concentration is too low for
accurate evaluation (< 10x MDL)
RA Relative Percent Difference (RPD) was not used for data
validation because the sample concentration is too low for
accurate evaluation (< 10x MDL)
RA Relative Percent Difference (RPD) was not used for data
validation because the sample concentration is too low for
accurate evaluation (< 10x MDL)
RA Relative Percent Difference (RPD) was not used for data
validation because the sample concentration is too low for
accurate evaluation (< 10x MDL)
RA Relative Percent Difference (RPD) was not used for data
validation because the sample concentration is too low for
accurate evaluation (< 10x MDL)
RA Relative Percent Difference (RPD) was not used for data
validation because the sample concentration is too low for
accurate evaluation (< 10x MDL)
RA Relative Percent Difference (RPD) was not used for data
validation because the sample concentration is too low for
accurate evaluation (< 10x MDL)
RA Relative Percent Difference (RPD) was not used for data
validation because the sample concentration is too low for
accurate evaluation (< 10x MDL)
HD Analysis is outside the intended scope of the method,
which does not provide hold time information for soil
extracts No hold time is observed for collection to
extraction The referenced method hold time is observed
for extraction -to- analysis
SM4500CI -E M1 Matrix spike recovery was high, the recovery of the
associated control sample (LCS or LFB) was acceptable
SM4500CI -E RA Relative Percent Difference (RPD) was not used for data
validation because the sample concentration is too low for
accurate evaluation (< 10x MDL)
WG330799 Fluoride (1312 DI) SM4500F -C RA Relative Percent Difference (RPD) was not used for data
validation because the sample concentration is too low for
accurate evaluation (< 10x MDL)
WG330670 Nitrate /Nitrite as N (1312 -DI) M353 2 - Automated Cadmium HD Analysis is outside the intended scope of the method,
Reduction which does not provide hold time information for soil
extracts No hold time is observed for collection to
extraction The referenced method hold time is observed
for extraction -to- analysis
Nitrite as N (1312 -DI) M353 2 - Automated Cadmium HD Analysis is outside the intended scope of the method,
Reduction which does not provide hold time information for soil
extracts No hold time is observed for collection to
extraction The referenced method hold time is observed
for extraction -to- analysis
M353 2 - Automated Cadmium RA Relative Percent Difference (RPD) was not used for data
Reduction validation because the sample concentration is too low for
accurate evaluation (< 10x MDL)
WG330656 Nitrogen, ammonia (1312 -DI) M350 1 - Automated Phenate HD Analysis is outside the intended scope of the method,
which does not provide hold time information for soil
extracts No hold time is observed for collection to
extraction The referenced method hold time is observed
for extraction -to- analysis
M350 1 - Automated Phenate RA Relative Percent Difference (RPD) was not used for data
validation because the sample concentration is too low for
accurate evaluation (< 10x MDL)
WG330669 Phosphorus, ortho dissolved (1312 -DI) M365 1 - Automated Ascorbic HD Analysis is outside the intended scope of the method,
Acid which does not provide hold time information for soil
extracts No hold time is observed for collection to
extraction The referenced method hold time is observed
for extraction -to- analysis
M365 1 - Automated Ascorbic RA Relative Percent Difference (RPD) was not used for data
Acid validation because the sample concentration is too low for
M6010B ICP
M6010B ICP
M6020 ICP -MS
M6010B ICP
M6020 ICP -MS
M6010B ICP
M6020 ICP -MS
M6020 ICP -MS
M6020 ICP -MS
SM4500CI -E
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