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MATERIAL SAFETY DATA SHEET,
<br />
<br />E°poaur•LImIY:
<br />VELA' ACGIH
<br />TLyD.
<br />STEL
<br />Onib
<br />Am&ectl, to^ 10'• ND mglm°
<br />(Z,d-Dicnbropnenoxy},
<br />isooq[ IT~msmeMl
<br />eabr
<br />'8-hour TWA unless otherwise noted.
<br />''Based on atloptetl limit f« 2,4-D.
<br />Ventilation:
<br />Where engineering controls are indicated by specifil
<br />use conditions or a potential for excessive exposure
<br />use local exhaust ventilation at the point of generation
<br />9. PHYSICAL AND CHEMICAL PROPERTIES
<br />NOTE: Physical data are ypical values, bN may vary
<br />from sample to sample. A ypiwl value should not be
<br />constmetl as a guaranteetl anatysis or as.a specifics
<br />lion.
<br />Phys(wl Appearance: Amber liquid. _
<br />Odor; Charaderistb phermlic.
<br />pH: Not Available.
<br />Specific Graviy: Approximatey 1.13
<br />Water Solubility: Product is emulsi(able in water.
<br />Melting Point Range: Not Available.
<br />Boiling Point Range: Not Available. Based on com-
<br />ponents, expected to be >200•C.
<br />Vapor Pressure: 3.6 x 10'° mm Hg Q 25'C (data
<br />on 2,4-D 2EHE)
<br />Molecular Weight: 333.27 (data on 2.4D 2EHE)
<br />10. STABILITY AND REACTIVfTY
<br />Chemical Stability: This material is stable untler rwr-
<br />mal handling and storage wndhions described in Sao-
<br />ibn 7,
<br />Conditions To Be Avoided: Excessive heat .
<br />Incompatibility With Other Materials: Strong oxidiz-
<br />ing agents: bases, acids.
<br />Hazardous Decomposltfon Products:-
<br />Decomposition Type: Themral
<br />Decomposltfon Products: Hytlrogen chbride, other
<br />chorine wmpountls, oxides of carbon and nitrogen.
<br />Hazardous Potymerization: Does rot occur.'
<br />11. TOXICOLOGICAL INFORMATION
<br />Toxicoldoical Data:
<br />Data on ih'6 product
<br />Eye Irrttation: Minimaly irritat'urg (Rabbtt).
<br />Skin Irritation: 51'ghty irritating (RabbR).
<br />Dermal: Blighty toxic. (Rabbit LD°D >2020 mg/kg).
<br />Inhalation: Slyhty toxb. (Rat4hr LCsD: >s.t2 mg/L)
<br />Oral: Stighty bxic. (Rat LDso 7380 mg/kg).
<br />This produm contains substances [hat are consitlered
<br />to be probable or suspected human carcinogens as
<br />follows:
<br /> Rpebrory Agency
<br />Listbp N Cardnegm
<br />Ingreabnb Nam• DSHA URC NTP ACGIN
<br />CnbropnenoryneMkitle• No Ta No No
<br />(Also see Section 3.)
<br />72. ECOLOGICAL INFORMATION
<br />Aquatic Toxici '
<br />Oafs on 2,4-D 2EHE or EC formublion:
<br />9fi-hr LCsD Blueglll: >5 mgll
<br />96-hr LC°p Rainbow Trout 7.2 ng0
<br />48-hr ECsD Daphnia: >5 ng4
<br />AA=an Toxici
<br />Data on 2,4-D 2EHE:
<br />Bobwhite Quail Dietary LCso: >5620 ppm
<br />Mallard Duck B-day Dietary LCsa: >5620 ppm
<br />Environmental Fate:
<br />In representative laboratory and field studies, 2,4D
<br />2EHE rapidty hydrolyzed to parent acid. The ypical
<br />haft-life of the resultant 2,4-D acid ranged from a few
<br />days to afew weeks.
<br />UPDATES AVAILABLE AT WWW.GREENBOOK.NET 2
<br />13. DISPOSAL CONSIDERATIONS
<br />Waste Disposal Method:
<br />Pesticide wastes are toxic. Improper disposal of ex•
<br />cess pesticide is a v'lolatpn of Federal Law and may
<br />contaminate grountl water. If these wastes cannot be
<br />disposed of by use acc«ding to label instructions,
<br />wntact your State Pesticide or Environmental Cbn-
<br />trol Agency, or the Hazardous Waste representative at
<br />the nearest EPA Regbnal Office for gubagde.
<br />Container Handling and Dlsposal:
<br />Do not reuse empy container. Triple dnsd (« equiv-
<br />alent) adding rinsate to application equipment Then
<br />otter empy container for recycling or reconditioning, «
<br />puncture and dispose of in a sanitary IandfO or by (r}
<br />cinemtion, «, if albwed by State and bcal audrorities,
<br />by burning. If burned stay out of smoke.
<br />14. TRANSPORTATION INFORMATION
<br />NOTE: Information is for surface transportation of
<br />-package sizes generally o0ered and does not address
<br />reguletory variations due to changes in package sae,
<br />mode of shipment or other conditions.
<br />Packages containing less Nan 15.5 gallons of this
<br />protlucl are genereuy not regulatetl. For packages
<br />containirg 15.5 gallons or higher.
<br />DOT Proper Shipping Name: ENVIRONMENTALLY
<br />HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (2,4D
<br />ESTER), RO (2,4-D ESTER)
<br />DOT Hazard Class I I.D. No.: 9 / UN3082
<br />DO7 Label: Class 9
<br />U.S. Surface Freight Classification: Weed killing
<br />wmpound, N.O.LB.N
<br />15. REGULATORY INFORMATION
<br />Federal Reaulatlons~
<br />TSCA Inventory: This protlum b excepted horn TSCA
<br />because R's soley for FIFRA'regulated use.
<br />SARA Hazard Notification:
<br />Hazard Categories Under Criteria of SARA Tttle III
<br />Rules (40 CFR Pad 370):
<br />FM: Rucrroc R•bwot Acub Cbonl[
<br />Pnamn: Hearin: NeapD:
<br />No No No Yss Ve•
<br />Section 373 Toxic Chemical(s):
<br />ACETIC ACID, (2,4-DICHLOROPHENOXY}, 2-
<br />ETHYLHEXYL ESTER, CAS NO- 792&x3-0 (86.6%
<br />by weight in produuY)
<br />Reportable Ouantfy (RO) under U.S. CERCLA;
<br />bgnbbin Ro
<br />ACETIC ACID, (T,d-DIC1aOROPNEND%V}. 100 W[
<br />]-ETMYLHE%YL ESTER
<br />Selected State Regulations:
<br />This product contains the following components that
<br />are regulatetl under OalSOmia Proposition 65:
<br />Inpr•tlbnl Cannr R•proeucav WF Lrv•I Iu014aY)
<br />N•ny Lbt Liar Lelllernb Nul•rm
<br />Nd Not Ap- NM Nor ' Not
<br />gpp°coDb plkaek gppr®Db App4oDM AppF
<br /> obb
<br />I6. OTHER INFORMATION
<br />vational Fire Protection Association (NFPAs) Haz-
<br />rrtl Ratings:
<br />RatMg• for Thb Preeuct xeY re Rarbpa
<br />z Hearin Haealb o ubim•I
<br />1 FbmmaDAry t Slgnr
<br />o inu,e°Dy z MaEer.l.
<br /> 3 scrota
<br /> d Sewn
<br />Lbbreviationc and Acronyms Not Defined Else-
<br />yhere:
<br />ICGIH American Conference of Governmental Indus-
<br />~ial Hygienists '
<br />JJSI American National Standards Institute
<br />:ERCLA Comprehensive Environmental Response.
<br />:ompensation and Liab7ily AC
<br />DOT Depanmen[ of 7ransportatbn
<br />FIFRA Federal Insecticltle, Fungicide aM Rodenticide
<br />Act
<br />IARC International Agency f« Research on Cancer '
<br />MSHA Mine Safey and HeaOh Administra0on
<br />NIOSH National Institute for Occupational Safey and
<br />Health
<br />NTP National Toxicology Program
<br />OSHA Occupational Satey and Health Administratbn
<br />PEL Pemtissible Exposure UMl
<br />SARA Superfuntl ~Amentlmenls and Real7thorization
<br />Act of 7986
<br />STEL Short Term Exposure Limit
<br />7LV Threshold Limit Value
<br />TSCA Toxic Substances CoIroW Act
<br />TWA Time Weghted Average
<br />USEPA U.S. Ernironmemal Protection Agenry
<br />This Material Safey Data Sheet (MSDS) serves dif-
<br />ferent purposes than and DOES NOT REPLACE OR
<br />MODIFY THE EPA-ACCEPTED PRODUCT LABEL'
<br />ING (attached to arW accompanying the produq con
<br />other), -The MSDS provides Important hea0h, salary
<br />and environmental inf«matioh for empbyers, empby-
<br />ees, emergency responders and others handling large
<br />quanittles o/ the product in actNities genealy other
<br />than product use, while the IabeGng provides that al-
<br />fomratlon speciflraly for product use N the ordinary
<br />course.
<br />Use, storage and d'ISposal of pesibide products are
<br />regulated by the EPA under the euthody of the Federal
<br />Insecticide, Fungicide, and Rodenticide Pct (FIFRA)
<br />through the product labeling, and all necessary and
<br />appropriate precamionary, use, st«age, and d'appsal
<br />informal'an is set forth on that labeling. It le a violation
<br />of federal bw to use a pesticide product in any manner
<br />not Drescnbed on the EPA-accepted label.
<br />AMough the informatbn and recommenda5ons set
<br />lonh hereb (hereinafter 'lntomlatipn°) are presemed
<br />in good fahh aM bellevetl to be comeq es of the
<br />date hereof, Nufarm,~lnc. makes norepresentatbns
<br />as to the completeness or accurary thereof. Inf«ma-
<br />tion is suppried uPOn the condkbn that the.persore
<br />receNing same will make their own determinatbn as
<br />to its suitability I« their purposes prior to use. !n ro
<br />event will NWarm, Inc. be responsible for damages
<br />of any nature whatsoever resulting from the use «of
<br />reliance upon Information. NO REPRESENTATIONS
<br />OR WARRANTIES. ERHER EXPRESS OR IMPLIED,
<br />OF MERCHAN7ABILfTY, FITNESS FOR A PARTIG
<br />ULAR PURPOSE OR OF ANY OTHER NATURE ARE
<br />MADE HEREUNDER WITH RESPECT TO INFORMA-
<br />TION OR THE PRODUCT TO WHICH INFORMATION
<br />REFERS.
<br />WEEDONEB is a registered trademark of Nufartn, Inc.
<br />VID 5.74.03
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