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In TRIM <br />COLORADO DEPARTMENT OF PUBLIC HEALTH AND ENVIRONMENT, Water Quality Control Division <br />Fact Sheet- Page 18, Permit No. C00000906 <br />008, and 010; where a semi-annual monitoring requirement was applied to outfall 001, semi-annual monitoring <br />was also required for outfalls 007, 008, and 010 <br />pH - This parameter is limited by the water quality standards of 6.5-9.0 s.u. for discharges from outfalls 001, <br />007, 008 and 010 as this range is more stringent than other applicable standards. <br />Total Arsenic <br />A quantitative RP analysis was conducted for outfall 001 based on the WQBEL and ADBAC as calculated in the <br />WQA. A qualitative RP analysis was conducted for outfalls 007, 008, and 010, as arsenic is identified in the <br />ELG Development Document as a parameter that can be found in alkaline coal -related discharges. <br />Outfall 001: the MEPC was greater than the MAPC and therefore limitations are typically required. <br />However, the temporary modification "As(ch)=current condition" applies to discharge from outfall 001 <br />through 12/31/2021; therefore, a report requirement is included in the permit for this permit term. <br />Outfalls 007, 008, and 010: a qualitative monitoring determination was made because the outfalls <br />transmit surface flow from the active mining area. The treatment provided by sedimentation ponds <br />approved under the SMCRA authority are not expressly designed for all pollutants regulated under the <br />WQCA, including metals removal, and for outfall 010, no treatment technology is implemented. Therefore, <br />a quarterly monitoring requirement was added to the permit for the collection of data for future RP <br />analysis. <br />Dissolved Arsenic <br />A quantitative RP analysis was conducted for outfall 001 based on the WQBEL and ADBAC as calculated in the <br />WQA. A qualitative RP analysis was conducted for outfalls 007, 008, and 010, as arsenic is identified in the <br />ELG Development Document as a parameter that can be found in alkaline coal -related discharges. <br />Outfall 001: dissolved arsenic data was not available; therefore, total arsenic was used as a conservative <br />estimate because dissolved arsenic is a subset of total arsenic. The MEPC was less than half of the MAPC <br />and therefore limitations and monitoring are not necessary at this time. <br />Outfalls 007, 008, and 010: a qualitative monitoring determination was made because the outfalls <br />transmit surface flow from the active mining area. However, monitoring for total arsenic will provide <br />sufficient data regarding the dissolved arsenic concentration in the discharge. Therefore, no monitoring <br />for dissolved arsenic is required at these outfalls. <br />Potentially Dissolved Cadmium <br />A quantitative RP analysis was conducted for outfall 001 based upon facility data and the WQBELs and ADBACs <br />as calculated in the WQA. A qualitative RP analysis was conducted for outfalls 007, 008, and 010 as cadmium <br />is identified in the ELG Development Document as a parameter that can be found in alkaline coal -related <br />discharges. <br />Outfall 001: Less than 30% of the sample results for dissolved cadmium were above the detection limit; <br />therefore, the MEPC could not be calculated. Monitoring data indicate that dissolved cadmium ranged <br />from non -detect to 0.1 pg/l with one sample result at 12 pg/l compared to the WQBEL of 0.86 pg/l. The 12 <br />pg/1 sample may be an outlier; however, the reported result must be considered and a quantitative <br />determination of RP was made. The 30 -day average, daily maximum and 2 -year average limitations are <br />included in the permit. This is a new limit and it is unknown if the permittee can consistently meet the <br />limit, therefore, a compliance schedule with interim limits based on monitoring data (the highest actual <br />30 -day average and daily maximum) was added to the permit to give the permittee time to meet this <br />Limitation. <br />Outfalls 007, 008, and 010: a qualitative monitoring determination was made because the outfalls <br />transmit surface flow from the active mining area. The treatment provided by sedimentation ponds <br />approved under the SMCRA authority are not expressly designed for all pollutants regulated under the <br />WQCA, including metals removal, and for outfall 010, no treatment technology is implemented. Therefore, <br />a quarterly monitoring requirement was added to the permit for the collection of data to support future RP <br />determinations. <br />