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<br />becomes a primary source of added heat and <br />possibly subsequent above normal evaporation. <br />The quantity Qe is the latent heat of vaporization. <br />It varies slightly with temperature at which the <br />process occurs but is close to 585 calories per gram <br />of water evaporaled at typical reservoir tempera- <br />tures. This parameter is included in the model. <br /> <br />Qh is the energy conducted out of the reservoir <br />as sensible heat. This represents a very small <br />portion of the heat budget (Harbeck, et al.. 1958) <br />which will become a negative influence on <br />suppression in summer and a positive influence in <br />winter. Analysis of the size of this parameter <br />compared to other factors in the energy budgets of <br />the USGS studies indicates that only negligible <br />error is introduced by ignoring the change in this <br />parameter caused by thermal mixing. <br /> <br />Qw is the energy advected by evaporated <br />water. This is the smallest of all items in the USGS <br />energy budgets and may be ignored (or could easily <br />be added to the latent heat computation QeJ. <br /> <br />In summary, two of the nine energy budget <br />parameters appear to dominate the calculation of <br />evaporation suppression secondary effects; these <br />are Qe (evaporation latent heat) and Qv (the <br />outflow component). It would appear that without <br />any outflow, there would be no net annual <br />suppression; that is, the savings during the summer <br />season would be essentially completely dissipated <br />by increased evaporation later during the decay of <br />residual heat added by suppression. However, <br />man-made impoundments do typically have large <br />outflows and the increased r-utflow temperature <br />should represent a significant net savings. <br /> <br />The importance of the beneficial effect of <br />outflow temperature increases due to destratifica- <br />tion is interesting in relation to previous research <br />on monolayer suppression. The fact that deep <br />outlet temperatures are not increased during <br />monolayer treatment suggests that the auded heat <br />from reduced evaporation would tend to limit <br />suppression by that melhod to a net seasonal <br />amount which would tend to approach zero when <br />analyzed on an annual basis. In addition to this <br />advantage of thermal mixing over the monolayer <br />concept in the long lerm. a similar advantage <br />occurs with daily suppression rates. During the <br />monolayer operation, above normal evaporation <br />begins immediately upon wind stripping of the <br />chemical film because of added heat which <br />accumulated near the surface during film coverage. <br />Although a similar amount of heat is added to the <br />water during suppression by thermal mixing, it is <br />continuously mixed and distributed equally <br /> <br />throughout the reservoir rather than concentrated <br />above the thermocline. At any point in time, <br />therefore. the surface temperature increase due to <br />suppression itself is much less than for the <br />monolayer method. <br /> <br />Summary of model conceptualIzation <br /> <br />The suppression by thermal mixing model <br />which has been described and justified in general <br />terms here and which is developed in detail in a <br />later section can be conceptualized in abbreviated <br />form as follows: <br /> <br />Basic Concept: Idealized suppression IS <br />calculated as a function of change in water surface <br />temperature (ergo change. in vapor pressure) <br />caused by perfect mixing (isothermal temperature <br />profile). <br /> <br />Secondary Effects: The secondary effects <br />which are sufficiently important to be included in <br />the model are: (I) added heat due to the decrease in <br />heat loss due to evaporation caused by suppression <br />during a previous period. and (2) heat loss from the <br />reservoir due to wam1er than normal outflow from <br />the mixed reservoir. <br /> <br />Time Resolution: Model Parameters will be <br />determined on a monthly average basis. Heat flux <br />will be accumulated between months up to six <br />months for reservoirs on which a seasonal (May to <br />October) analysis is appropriate and for annual or <br />multi-year periods where carryover storage is <br />important. <br /> <br />Errors In the model <br /> <br />A source of error which has not been discussed <br />previously is that the model assumes perfect <br />thermal mixing: that is, conversion of the normal <br />thermocline into an isothermal temperature <br />profile. Results on many reservoirs which have <br />been mixed for water quality objectives indicate <br />that this is feasible except for a very minor diurnal <br />variation on the order of ICe. Many of the <br />empirical results did not achieve this degree of <br />mixing because pumping was limited to that <br />necessary for desired dissolved oxygen levels. But <br />those projects on which pumping with sufficiently <br />large energy sources were operated continuously <br />seemed to produce almost perfect mixing. No <br />correction for this non.conservativE': error was <br />incorporated into the model since it is considered to <br />be relatively small. <br /> <br />14 <br />