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ACZ Laboratories, Inc. <br />2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334 -5493 <br />Rio Grande Silver, Inc. <br />ACZ ID WORKNUM PARAMETER <br />METHOD QUAL DESCRIPTION <br />REPAD.15.06.05.01 <br />validation because the sample concentration is too low for <br />accurate evaluation (< 10x MDL). <br />M6020 ICP -MS RA Relative Percent Difference (RPD) was not used for data <br />validation because the sample concentration is too low for <br />accurate evaluation (< 10x MDL) <br />M6020 ICP -MS RA Relative Percent Difference (RPD) was not used for data <br />validation because the sample concentration is too low for <br />accurate evaluation (< 10x MDL) <br />M6020 ICP -MS RA Relative Percent Difference (RPD) was not used for data <br />validation because the sample concentration is too low for <br />accurate evaluation (< 10x MDL). <br />M6020 ICP -MS ZB The ICP -MS Serial Dilution was not used for data validation <br />because the sample concentration was less than 100 times <br />the MDL <br />WG340317 Neutralization Potential as CaCO3 M600/2 -78 -054 3 2 3 RA Relative Percent Difference (RPD) was not used for data <br />validation because the sample concentration is too low for <br />accurate evaluation (< 10x MDL) <br />WG340300 Sulfur Organic Residual M600/2 -78 -054 3 2 4-MOD RA Relative Percent Difference (RPD) was not used for data <br />validation because the sample concentration is too low for <br />accurate evaluation (< 10x MDL) <br />Sulfur Sulfate M600/2- 78-054 3 2 4-MOD RA Relative Percent Difference (RPD) was not used for data <br />validation because the sample concentration is too low for <br />accurate evaluation (< 10x MDL). <br />WG340407 Chloride (1312 DI) SM4500CI -E HD Analysis is outside the intended scope of the method, <br />which does not provide hold time information for soil <br />extracts No hold time is observed for collection to <br />extraction The referenced method hold time is observed <br />for extraction - to-analysis. <br />SM4500CI -E RA Relative Percent Difference (RPD) was not used for data <br />validation because the sample concentration is too low for <br />accurate evaluation (< 10x MDL) <br />WG340398 Fluonde (1312 DI) SM4500F -C RA Relative Percent Difference (RPD) was not used for data <br />validation because the sample concentration is too low for <br />accurate evaluation (< 10x MDL) <br />WG340357 Nitrate /Ndnte as N (1312 -DI) M353 2 - Automated Cadmium HD Analysis is outside the intended scope of the method, <br />Reduction which does not provide hold time information for soil <br />extracts No hold time is observed for collection to <br />extraction The referenced method hold time is observed <br />for extraction - to-analysis <br />M353.2 - Automated Cadmium RA Relative Percent Difference (RPD) was not used for data <br />Reduction validation because the sample concentration is too low for <br />accurate evaluation (< 10x MDL). <br />Nitrite as N (1312 -DI) M353 2 - Automated Cadmium HD Analysis is outside the intended scope of the method, <br />Reduction which does not provide hold time information for soil <br />extracts No hold time is observed for collection to <br />extraction. The referenced method hold time is observed <br />for extraction - to-analysis. <br />M353 2 - Automated Cadmium RA Relative Percent Difference (RPD) was not used for data <br />Reduction validation because the sample concentration is too low for <br />accurate evaluation (< 10x MDL) <br />WG340458 Nitrogen, ammonia (1312 -0I) M350 1 - Automated Phenate HD Analysis is outside the intended scope of the method, <br />which does not provide hold time information for soil <br />extracts. No hold time is observed for collection to <br />extraction The referenced method hold time is observed <br />for extraction - to-analysis <br />M350.1 - Automated Phenate RA Relative Percent Difference (RPD) was not used for data <br />validation because the sample concentration is too low for <br />accurate evaluation (< 10x MDL). <br />WG340358 Phosphorus, ortho dissolved (1312 -DI) M365 1 - Automated Ascorbic HD Analysis is outside the intended scope of the method, <br />Acid which does not provide hold time information for sod <br />extracts. No hold time is observed for collection to <br />extraction The referenced method hold time is observed <br />for extraction - to-analysis <br />M365.1 - Automated Ascorbic RA Relative Percent Difference (RPD) was not used for data <br />Acid validation because the sample concentration is too low for <br />accurate evaluation (< 10x MDL) <br />WG340405 Sulfate (1312 DI) D516 -02 - Turbidimetric HD Analysis is outside the intended scope of the method, <br />which does not provide hold time information for soil <br />Thallium (1312) <br />Uranium (1312) <br />WG340757 Zinc (1312) <br />Inorganic Extended <br />Qualifier Report <br />ACZ Project ID: L11050 <br />Page 31 of 38 <br />