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ACZ Laboratories, Inc. <br />2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334 -5493 <br />Rio Grande Silver, Inc. <br />Project ID: S12064 <br />Sample ID: WRSF -B <br />Wet Chemistry <br />Parameter <br />EPA Method <br />Result Qual XQ Units MDL PQL <br />Date Analyst <br />Alkalinity (1312 DI) <br />Bicarbonate as <br />CaCO3 <br />Carbonate as CaCO3 <br />Hydroxide as CaCO3 <br />Total Alkalinity <br />Chloride (1312 DI) <br />Fluoride (1312 DI) <br />Nitrate (1312 DI) <br />Nitrate /Nitrite as N <br />(1312 -DI) <br />Nitrite as N (1312 -DI) <br />Nitrogen, ammonia <br />(1312 -DI) <br />Phosphorus, ortho <br />dissolved (1312 -DI) <br />Sulfate (1312 DI) <br />SM2320B - Titration <br />SM4500CI -E <br />SM4500F -C <br />Calculation: NO3NO2 minus NO2 0 03 <br />M353.2 - Automated Cadmium 0 05 <br />Reduction <br />M353 2 - Automated Cadmium 0 02 BH <br />Reduction <br />M350 1 - Automated Phenate U <br />M365 1 - Automated Ascorbic <br />Acid <br />D516 -02 - Turbidimetric <br />3 <br />U <br />U <br />U <br />B <br />U <br />U <br />BH <br />BH <br />0 03 BH <br />* mg /L <br />* mg /L <br />* mg /L <br />* mg /L <br />* mg /L <br />mg /L <br />* mg /L <br />U • mg /L <br />ACZ Sample ID: <br />Date Sampled: <br />Date Received: <br />Sample Matrix: <br />Inorganic Analytical <br />Results <br />mg /L 2 20 10/15/12 0 00 abm <br />2 <br />2 <br />2 <br />1 <br />0.1 <br />0.02 <br />0.02 <br />20 <br />20 <br />20 <br />5 <br />05 <br />01 <br />0.1 <br />L97087 -02 <br />09/28/12 13:56 <br />10/02/12 <br />Soil <br />10/15/12 0 00 <br />10/15/12 0 00 <br />10/15/12 0 00 <br />10/16/12 9:48 <br />10/15/12 11:54 <br />10/22/12 11.39 <br />10/12/12 23 17 <br />abm <br />abm <br />abm <br />Ihb <br />abm <br />ca lc <br />pjb <br />mg /L 0 01 0 05 10/18/12 23:50 pjb <br />mg /L 0 05 0 5 10/18/12 13 23 tcd <br />mg /L 0 01 0 05 10/12/12 22:25 pjb <br />1 5 10/17/12 15:53 Ihb <br />REPIN 02 06 05.01 * Please refer to Qualifier Reports for details <br />Page 8 of 57 <br />