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A CZ Laboratories, Inc. <br />2773 Downhil Drive Steamboat Springs, CO 80487 (800) 334 -5493 <br />Karr Coal Company <br />Project ID: <br />Sample ID: AP -2 <br />Field Data <br />Conductivity (Field) <br />pH (Field) <br />Temperature (Field) <br />Metals Analysis <br />Field Measurement <br />Field Measurement <br />Field Measurement <br />Calcium, dissolved A4200.7 ICP <br />Iron, dissolved M200.7 ICP <br />Magnesium, dissolved M200.7 ICP <br />Manganese, dissolved M200.7 ICP <br />Potassium, dissolved M200.7 ICP <br />Sodium, dissolved M200.7 ICP <br />Wet Chemistry <br />Residue, Fikerab e <br />(TDS) ©180C <br />Sodium Absorption <br />Ratio kr Water <br />Sulfate <br />TDS (calculated) <br />TOS (ratio - <br />measured/calculated) <br />REPIN.02.06.05.01 <br />SM23208 - Titration <br />Alkalinity as CaCO3 <br />Bicarbonate as <br />CaCO3 <br />Carbonate as CaCO3 <br />Hydroxide as CaCO3 <br />Total Alkalis y <br />Cation -Anion Balance Calculation <br />Cation-Anion Balance <br />Sum of Anions <br />Sum of Cations <br />Chloride <br />Hardness as CaCO3 <br />Lab Filtradon <br />Lab Fikration & <br />Acidification <br />Nitrate as N, dissolved <br />Nitrate/Nitrite as N, <br />dissolved <br />Nitrite as N, dissolved <br />M325.2 - Colorimetric <br />SM23408 - Calculation <br />SM 3030 8 <br />SM 3030 B <br />Calculation: NO3NO2 minus NO2 <br />M353.2 - Automated Cadmium <br />Reduction <br />M3532 - Automated Cadmium <br />Reduction <br />M160.1 - Gravimetric <br />USGS - 11738 -78 <br />M375.3 - Gravimetric <br />Calculation <br />Cakxdation <br />200 <br />8.0 <br />13.0 <br />63.8 <br />0.34 <br />43.1 <br />0.362 <br />2.1 <br />47.1 <br />381 <br />381 <br />1.7 <br />8.6 <br />8.9 <br />7 <br />337 <br />1.13 <br />40 B <br />433 <br />0.95 <br />mg/L <br />mg& <br />mg/L <br />mg/L <br />• mg/L <br />• mg/L <br />ACZ Sample ID: <br />Date Sampled: <br />Date Received: <br />Sample Matrix: <br />umhos/cm <br />units <br />C <br />mg& <br />'16 <br />meq/L 0.1 <br />meq/L 0.1 <br />mg/L 1 <br />mg/L 1 <br />0.04 B mg/L 0.02 <br />0.04 BH mg/L 0.02 <br />'organic Artaiyticai <br />Resits <br />PA? aitx >t <br />EPA Met£ietti <br />< ti�3su4t> Qcr; £ Xf? Unit% ; Mf Ls <br />Parfrmator <br />EPA Mntflod. <br />Rexut Oita; X11 tFr+t3a MOL PO L.. <br />Ante Avoi}tst <br />0.2 <br />0.02 <br />0.2 <br />0.005 <br />0.3 <br />0.3 <br />1 <br />0.05 <br />1 <br />0.03 <br />1 <br />1 <br />0.5 <br />0.5 <br />5 <br />7 <br />L53815-02 <br />10/18(0511:45 <br />10/19/05 <br />G ound Water <br />10/18/05 11:45 <br />10/18/0511:45 <br />10/18/05 11:45 <br />10/22/05 20:23 <br />10/22/05 20:23 <br />10122/05 20:23 <br />10/22/05 20:23 <br />10/22/05 20:23 <br />10/22/05 20:23 <br />2 20 10/28/05 0:00 <br />U mg/L 2 20 10/28/05 0:00 <br />U mg/L 2 20 10/28/05 0:00 <br />mg/L 2 20 10/28/05 0:00 <br />11/10/05 0:00 <br />11/10/05 0:00 <br />11/10/05 0:00 <br />11 /07/0512:27 <br />11/10/05 0:00 <br />10/28/05 2:40 <br />10/20/0511:51 <br />0.1 11/10/05 0:00 <br />0.1 10/20/0519:23 <br />410 mg/L 10 20 10/24/0514:20 <br />• mg/L 10 50 11 /02/0518:07 <br />mg&L 10 50 11/10/05 0:00 <br />11/10/05 0:00 <br />mea <br />mea <br />mea <br />mea <br />mw <br />mea <br />PO :KUM' EP <br />atattmad <br />Rot uti Qtzst <br />MQL P4.2L <br />Gate Analyst <br />I L53815: Page 3 of 17 1 <br />Id <br />ld <br />Id <br />Id <br />calc <br />caic <br />celc <br />ccp <br />caic <br />tam <br />do <br />celc <br />pib <br />U mg/L 0.01 0.05 10/19/0518:36 pJb <br />Id <br />0.03 0.15 11/10/05 0:00 sic <br />cork: <br />caic <br />• Phase refer to Extended QuaMfler Report for detet <br />