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IZ Laboratories, Inc. <br />2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334 -5493 <br />Karr Coal Company <br />Project ID: <br />Sample ID: AP -2 <br />Field Data <br />Conductivity (Field) <br />pH (Field) <br />Temperature (Field) <br />Metals Analysis <br />Calcium, dissolved <br />Iron, dissolved <br />Magnesium, dissolved <br />Manganese, dissolved <br />Potassium, dissolved <br />Sodium, dissolved <br />Wet Chemistry <br />Alkalinity as CaCO3 <br />Bicarbonate as <br />CaCO3 <br />Carbonate as CaCO3 <br />Hydroxide as CaCO3 <br />Total Alkalinity <br />Cation -Anion Balance <br />Cation -Anion Balance <br />Sum of Anions <br />Sum of Cations <br />Chloride <br />Hardness as CaCO3 <br />Lab Filtration <br />Lab Filtration & <br />Acidification <br />Nitrate as N, dissolved <br />Nitrate/Nitrite as N, <br />dissolved <br />Nitrite as N, dissolved <br />Residue, Filterable <br />(TDS) @180C <br />Sodium Absorption <br />Ratio in Water <br />Sulfate <br />TDS (calculated) <br />TDS (ratio - <br />measured/calculated) <br />REPIN.02.06.05.01 <br />Field Measurement <br />Field Measurement <br />Field Measurement <br />A4200.7 ICP <br />14200.7 1CP <br />M200.7 ICP <br />14200.7 ICP <br />M200.7 1CP <br />Al200.7 ICP <br />SM2320B - Titration <br />Calculation <br />M325.2 - Colorimetrtc <br />SM23406 - Calculation <br />S14 3030 B <br />SM 3030 B <br />Calculation: NO3NO2 minus NO2 <br />14353.2 - Automated Cadmium <br />Reduction <br />M353.2 - Automated Cadmium <br />Reduction <br />14160.1 - Gravknetric <br />USGS - 11738 -78 <br />SM4500 SO4 -D <br />Calculation <br />Calculation <br />945 <br />7.9 <br />12.2 <br />75.4 <br />0.31 <br />58.5 <br />0.215 <br />1.8 <br />115 <br />514 <br />514 <br />3.4 <br />12.8 <br />13.7 <br />14 <br />429 <br />670 <br />100 <br />674 <br />0.99 <br />u <br />u <br />u <br />u <br />u <br />umhos/cm <br />units <br />C <br />m <br />mL <br />mg/L <br />m9IL <br />m94- <br />mg/L <br />mg/L <br />mg/L <br />mg/L <br />mg/L <br />megJL <br />mg/L <br />mL <br />mg/L <br />mg/L <br />mg/L <br />• mg/L <br />ACZ Sample ID: <br />Date Sampled: <br />Date Received: <br />Sample Matrix: <br />Inorganic Analytical <br />Results <br />0.2 <br />0.02 <br />0.2 <br />0.005 <br />0.3 <br />0.3 <br />0. <br />0.1 <br />1 <br />1 <br />1 <br />0.05 <br />1 <br />0.03 <br />1 <br />1 <br />0.5 <br />0.5 <br />5 <br />7 <br />L56030 -07 <br />04/12/06 1 &10 <br />04/13/06 <br />Ground Wader <br />Pa; an etas <br />EPA flood <br />Rte ult Qua£ X0 Units M13L : P0L... t?attt Px32t1ysE <br />04/12/06 3:10 <br />04/12/06 3:10 <br />04/12/06 3:10 <br />04120/0618:21 <br />04/20/06 18:21 <br />04/20/06 18:21 <br />04/19/06 19:55 <br />04/19/06 19:55 <br />04/20/06 18:21 <br />2 20 04/13/06 0:00 <br />2 20 04/13106 0:00 <br />2 20 04/13/06 0:00 <br />2 20 04/13/06 0:00 <br />04/25/06 10:15 <br />04/25/06 10:15 <br />04/2906 10:15 <br />04/18/06 12:28 <br />04/25/0610:15 <br />04/18/0610:16 <br />04/18/06 15:27 <br />0.02 0.1 04/13106 18:45 <br />10 20 04/18/0615:12 <br />10 50 04/18/06 18:15 <br />10 50 04/25/0610:15 <br />04/25/06 10:15 <br />Perat t tar <br />EPA tolsttsnwl <br />xutf Okzas X€1 " 'tfn�t 144131 <br />'01 <br />tx Mo <br />1 <br />iC <br />iC <br />k <br />10 <br />Partto ator <br />EPA 1Htat*1443 <br />x+t£ i1113b t <br />fitair Arlatpst <br />L56030: Page 8 of 19 l <br />0 <br />0 <br />calc <br />ClaC <br />talc <br />nPs <br />celc <br />nPs <br />erf <br />0.02 0.1 04/25/06 10:15 calc <br />PIP <br />0.01 0.05 04/13/06 18:45 ptb <br />1 <br />2.44 0.03 0.15 04/25/0610:15 nic <br />0 <br />talc <br />talc <br />• Please refer to Extended Qualifier Report for detail. <br />