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water quality is expected to deteriorate in the down dip direction as well as toward areas with <br />higher overburden thickness. The thickest overburden in the NHN permit area is in the southern <br />one third of the area, (see Map 2.04.6 -3). <br />Underburden Zone Ground Water Quality The quarterly Under - burden Zone ground water <br />sample analyses from holes GW -N47, GW -N50, and GW -N53 are contained in Appendix <br />2.04.7 -1 along with the hydrographs and water level data. These three holes have been <br />monitored and samples collected since October 10, 2008. Review of TDS and SO from the three <br />holes show that holes GW -N47 and GW -N50 (see Map 2.04.7 -1 for hole locations) have poorer <br />water quality than the Coal Zone at the two corresponding sites; whereas, the Under - burden <br />Zone water quality at hole GW -N53 is better than the coal zone quality for that site. The shallow <br />depth of the coal zone at the two holes, GW -N47 and GW -N50, indicates that weathering has <br />removed (oxidized) at least to some degree the higher sulfur content that is to be expected in the <br />coal zone. The poorest water quality of the three new Underburden Zone holes is at GW -N47 <br />located in the northeast corner of the NHN permit area. This condition differs significantly from <br />the overburden and coal zones where the poorest quality water was at the southwestern site or at <br />holes GW -N54 and GW -N55. This suggests that the area of primary recharge for the under - <br />burden in the northwest corner of the NHN Permit area may be other than the 2 Park Lateral. <br />Table 2.04.7 -3 summarizes the ground water quality from the analyses of the samples from the <br />three underburden monitoring holes. The WQCC ( Regulation 41) water quality standards are <br />also included on this table for comparison with the underburden samples. Sulfate exceeds the <br />drinking water standards at all three holes while iron and manganese exceed drinking water <br />standards at holes GW -N47 and GW -N50. <br />Springs and Seeps <br />Three springs were defined in and in close proximity to the southern part of the NHN permit area <br />by Peabody at the old Nucla Mine, (see Map 2.04.7 -1). Two of these springs were at the toe of <br />the old backfill area (spoils) while the third was a spring issuing from the high -wall of the Nucla <br />Mine after mining ceased in 1983. These three "springs" were monitored from 1983 through <br />1987. The water quality and flow data for spoil springs SS #1,SS #2 and SS #3 are contained in <br />the Appendix of Section 2.04.7 -2. Spoil Spring (SS) #1 is located along a reclaimed drainage at <br />the toe of the backfill of the old Nucla Mine. SS #2 was located about 50 yds up- stream and to <br />the west of SS #1. The high -wall spring issued from the base of the overburden zone at or very <br />near to the contact with the coal zone. The flow of all three of these springs appeared to vary <br />with the seasonal irrigation, (see New Horizon 1 Mine Area permit). Flow rate varied from a <br />16.6 gpm to about 47 gpm during the irrigation season at SS #1 to a rate of 16.6 gpm to 32 gpm <br />during non - irrigation periods. SS #3 had a much lower flow rate estimated at about 0.3 gpm <br />during the fall of 1986. The only quantifiable flow rates from the high -wall (SS #3) were during <br />the irrigation season and were measured at about 4.5 gpm. Spoil Spring #3 (SS #3) in the <br />highwall was covered with backfill material when the old Peabody highwall was reclaimed in <br />1992. During 2001, SS #1 was again monitored (part of close out monitoring for old Peabody <br />permit area) and the data from this monitoring is included in the Appendix2.04.7 -2 to this <br />section. While water quality was similar at SS #1 from 1987 to 2001, the flow rate appears to <br />have increased 3 to 4 fold. The only explanation for this is that the surface owner has been <br />irrigating (running water over the old highwall reclaimed and backfilled slope) since 1992 to <br />enhance grazing opportunities. <br />Section 2.04.7 Page 10 November 2011 <br />