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Cotter Corporation (N.S.L.)'s Response to December 14, 2010 Adequacy Review, <br />Comments 10, 11C <br />Page 5, Item 10 — Charge Balance on Mine Water Samples from Upper Workings <br />Provide comment on the significance of the reported charge imbalance of - 46.77% for the <br />speciation calculation for the average water quality of the upper mine workings reported in <br />Section 14(b)(iii),I.I. Does it indicate a deficiency in the cation analysis, and if so which <br />cation(s), or is it more an artifact of the averaging? <br />RESPONSE: <br />The charge imbalance could indicate a missing cation or laboratory errors in the original <br />analysis. The original laboratory results for sample ILLRS, which were summarized in Table <br />14 -5 of the EPP, indicate that the laboratory reported TDS concentrations (11,000 mg/L) were <br />inconsistent with the reported electrical conductivity (7,190 uS /cm). This difference alone <br />accounts for the reported charge imbalance. Therefore it is believed that the charge imbalance is <br />likely due to analytical error for sulfate. <br />As noted by Hem (1985): <br />Water having dissolved - solids concentrations much greater than 1,000 mg/L tends <br />to have large concentrations of a few constituents. In such water, the test of anion - <br />cation balance does not adequately evaluate the accuracy of the values of the <br />lesser constituents. <br />Hem, John D., 1985. Study and Interpretation of the Chemical Characteristics of Natural Water, <br />Third Edition, U.S. Geological Survey Water Supply Paper 2254. 263 pp. <br />Page 6, Item 11(C) — Geochemical Studies on sorption /precipitation in Ralston Creek <br />1 <br />Section 15(a) (iv), page 15 -3. The EPP states that "sorption and precipitation processes remove <br />uranium from solution." Have any geochemical studies been conducted to verify that those <br />processes are indeed occurring in the stream and are removing uranium? <br />RESPONSE: <br />May 4, 2011 <br />Recent studies have not been performed to verify that sorption and precipitation processes <br />remove uranium from solution in Ralston Creek. Therefore, while the referenced figure (11 -6) <br />shows a decline in uranium concentrations along the 1.6 -mile flow path downstream of the mine, <br />the processes contributing to this decline could include dilution as well as (or instead of) sorption <br />and precipitation. <br />A study of stream waters in the Denver West Quadrangle conducted by the USGS (Zielinski, <br />2007) indicated that sorption was more likely affecting uranium concentrations than <br />precipitation: <br />