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. 2.04.6(2) <br />Geochemical Analysis <br />(b) The cores from two exploratory holes were analyzed <br />for geochemical parameters to identify physical and chemical <br />properties of the overburden, interburden and the stratum immedi- <br />ately below the lowest coal seam to be mined and the extent of any <br />materials which may have an adverse effect on the environment. The <br />two exploratory holes used were CC-1-90 and CC-3-90 both of which <br />are within the proposed permit area. <br />No significant ground water is expected to discharge <br />though the spoil piles or through the regraded surface. The <br />potentiometric surface of the ground water in the area is some 100 <br />feet below the lowest coal seam to be mined and impermeable layers <br />of shale totaling about 20-feet thick, exist between L-he lowest <br />coal seam to be mined and the aquifer. See section 2.04.7 for a <br />further description of this aquifer. <br />The main concern with the physical and chemical <br />properties of the overburden/interburden is whether any material <br />exists that will adversely effect reclamation. Following is an <br />interpretive summary to compare the analytical results obtained <br />from the samples with established guidelines so potential problems <br />with reclamation can be identified. Results are compared with the <br />suggested guidelines of the Wyoming Department of Environmental <br />Quality ,(DEQ), guideline No. 1 dated November 1984 or the Montana, <br />Department of State Lands Guidelines, (DSL). <br />~H The pH values of the eleven samples ranged <br />from 3.6 to 7.6 with an average of 6.2. The DEQ sets a suitable pH <br />range for overburden and regraded spoil from 5.5-8.5 with a <br />marginal range of 5.0-9.0. Two of the samples had pH values of <br />less that 5.0. Both were in the CC-1-90 core hole immediately <br />above and below the lowest coal seam to be mined. The sample <br />immediately below the lowest coal seam will not be disturbed so it <br />is not a concern regarding vegetation. The pH value for the sample <br />immediately above the coal seam was 4.4. It is probable that the <br />overburden removal process will mix this low pH material with the <br />overburden material above which has a pH of 7.4 and the resulting <br />blend will result in a suitable pH for overburden and regraded <br />spoils. The reclamation plan will provide for a monitoring plan to <br />delineate any unsuitable areas of regraded overburden with respect <br />to pH. The results of the monitoring plan are presented in Exhibit <br />7 beginning on page 7-32. <br />From a visual observation of the core material and specifi- <br />cally the material that exhibits a low pH, it is evident that <br />pyritic sulfur is the cause of the low pH. <br />C J <br />2.04-8 September 1994 <br />