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Environmental Protection Plan, Schwartzwalder Mine 11-54 <br />• Table 11-9. Uranium Concentrations in Ralston Creek, 1990 - Jan 2009 (Part 4) <br />SW-AWD <br />Date U m SW-A001 <br />Date U m SW-DIS001 <br />Date U (-gjL) SW-BPL <br />Date U m SW-FBRG <br />Date U m /L SW-ARH <br />Date U m SW-LLHG <br />Date U m /L <br /> 9/30/08 0.72 12/30/08 0.386 <br /> 10/28/08 0.277 1/20/09 0.307 <br /> 11/19/08 0.29 <br /> 12/30/08 0.387 <br /> 1/20/09 0.307 <br />(iii) Summary of Water Quality Impacts to Ralston Creek <br />Interaction with groundwater in the alluvium and fill has affected the water quality in Ralston Creek since <br />the sumps were shut down in June, 2002 (Section I l(c)(ii). The four collector trenches and pumpback <br />sumps were installed in the alluvium and fill during 1990 and 1991, and operated until June, 2002. Much <br />of the fill has been in place since the 1960s, when Ralston Creek was re-routed to the north side of the <br />canyon and mine facilities were constructed on the artificial fill. <br />Areas of contamination in and above the fill have been excavated and removed, in accordance with the <br />Mine Reclamation Plan (Cotter, 1983). The remaining fill material is not slated for removal. <br />Based on the existing conditions, water quality in Ralston Creek is expected to continue to show distinct <br />seasonal variation in uranium concentrations. High creek flows in the spring will result in low uranium <br />concentrations, well below the water supply intake standard (40 pCi/L, 0.059 mg/L) and the acute (4.12 <br />mg/L) and chronic (2.57 mg/L) aquatic toxicity standards (calculated in Section 11(a)(ii)). Low creek <br />flows in the winter and late summer will result in increased uranium concentrations, which may sometimes <br />exceed the water supply intake 20 standard but are unlikely to ever exceed the aquatic toxicity standards. <br />The source of the increased uranium and TDS in Ralston Creek is believed to be from diffuse sources in the <br />• fill material. Geochemical modeling of water under oxidizing conditions has not indicated a limiting <br />control for uranium solubility. Rather, uranium concentrations are controlled by reaction kinetics, the <br />velocity of groundwater flow within the alluvium and fill, and seasonal fluctuations in water levels. <br />Seasonal fluctuations in water levels expose uraniferous fill to oxidizing conditions during low water <br />periods. Infiltrating water which contacts these reactive surfaces solubilizes the stored uranium salts and <br />transports uranium into the groundwater system. Groundwater in the alluvium and fill interacts with <br />surface water in Ralston Creek, resulting in elevated uranium concentrations in the creek during certain <br />times of the year. <br />Uranium concentrations in Ralston Creek peaked within the first six months of turning off the sumps in <br />2002 (and turning off the Sump 1 recirculation in 2008). In 2002-2003, the reactive surfaces had been <br />exposed for over a decade while the sumps were in operation. The "first flush" of uranium removed from <br />the sump drains, fill, and alluvium was the "worst case" condition. Concentrations spiked, then came down <br />in sampling events. A similar spike occurred in 2008, several months after the cessation of Sump 1 <br />recirculation, after which concentrations began to trend downward. However, uranium concentrations <br />during low flow period are not expected to fall below about 0.2 mg/L, the observed concentrations during <br />low flow (Fall 2003) after the initial flush. <br />The waste rocks dumps have had no discernable effect on water quality in Ralston Creek. Water quality at <br />stations upgradient and downgradient of the reclaimed waste rock dumps shows negligible increases in <br />uranium, and slight decreases in TDS. <br />20 The nearest water supply intake (Moffat Water Treatment Plant) receives combined flows from Ralston Creek and South Boulder <br />Reservoir (Section 8(a)(i).2). These waters mix in Ralston Reservoir, with significantly more flow from South Boulder <br />•. Reservoir than from Ralston Creek. Therefore, although the comparison is made between water quality in Ralston Creek and <br />intake standards, water in the creek does not feed directly into any water supply intake without mixing. <br />4109C.090807