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The CDHG has requested an explanation fox the excaedence of the TDS value over the PHC <br />prediction at Well WHAI.7-2. The June-Sept:uohex TDS value measured this year was 1980 • <br />mg/1, while the predicted value ras 1299 mg/1. The 1480 mg/1 value was determined <br />gravime trically (i.e., dry a water sample an~f weigh the residue). According to Hem (1989, <br />pg. 357), .. it is not uncommon for water high in calcium and sulfate concentrations to <br />yield a residue after drying an hour at 180°C that exceeds the computed dissolved solids <br />by several hundred milligrams per liter" antl also, "In many instances, especially if the <br />concentration is greater than 1000 mg/1, the calculated draeolved-aolida value may be <br />preferable to the residue -on-evaporation value". The calculated dissolved aolida value is <br />determined by adding up all the eoncentrationa fox all of th¢ various dissolved <br />constituents. For June-September 1999, the calculated TDS value ie 1180 mg/1, rhich falls <br />below the PHC predicted value. Likewise, in the 1998 ARR, the 1433 mq/1 annual average <br />TDS value (June-September 1440 mg/1) vas the measured (gravimetric) value; the <br />calculated annual average TDS value was 1273 mg/1 (June-September = 1170 mg/1), which both <br />fall below the predicted value. (In the 1998 AHR, annual average TDS values for the <br />alluvium were used. It ass diacovexed by the rri ter thin year that the Seneca II-W PqC <br />uses June-September values. June-September values fox the alluvium aza being used in this <br />year's AHR). <br />- W <br />d <br />O <br />b <br />d F <br />a <br />qe <br />ver <br />ur <br />en. aux cells monitor the Wedge overburden . Wall WOV19 exhibits a <br />recently increasing TDS trend. At Wall WOVlfi, the limited at so faz indicates an <br />increasing TDS trend. (Only six samples have bean collected eo fnx for Well Wt7V16, until <br />recently there ras normally not enough water to sample). Well WOV17 exhibits an <br />increasing TDS trend. Well WOV4-1 (II-W South Expansion area) ras sampled for the first <br />time ewr this Hay. <br />The Seneca II-W PHC pxediote aMUal average TDS values at various Wadqe overburden re119. <br />For Well WOV14, a value of 4385 mg/1 ras predicted, while a value of 3645 mg/1 ras <br />observed this year. For Well WOV17, a value of 4295 mg/1 ras predicted, chile a value of <br />8935 mg/1 ras observed. This predicted value (42951 ras predicated on a premining value <br />of 6072 vg/1, rhich is an average of several overburden calls. Horever, Wall WOV17 <br />exhibited a preauning TDS average value of 8043 mg/1. <br />The CDHG, in [heir ravier of the 1998 AHR, raqueated on explanation of the TDS axcaedence <br />of the PHC prediction for Well WOV17. The source of the high baseline TDS values is <br />unknorn. This roll had a baseline TDS average of 8043 ag/1, chile the next highest TOS <br />• <br />