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<br />Mr. Richard Mills - 2 - March 27, 1986 <br />C. An interpretation of trends in water quality on a seasonal basis, <br />on an annual basis, and in comparison with baseline data; and, <br />D. An evaluation comparing the year's results with those predicted by <br />the Probable Hydrologic Consequences (PHC) section of the permit, and a <br />re-evalution of the PHC if appropriate. <br />Analytical Quality Assurance <br />The Division randomly evaluated some of the data to ascertain its quality. <br />Mass balance calculations and an assessment of the equivalence of total <br />dissolved solids with major ions concentrations were run. Cations ran <br />approximately ten percent (10%) lower than anions, although some runs showed <br />cations being thirty percent (30%) lower than solids. This data is of <br />acceptable quality, but a routine calculation of mass balance on all full <br />suite analyses would signal the necessity to rerun a sampling to improve <br />overall quality of the data. <br />C~iLRD observed that the analytical laboratory is routinely not attaining <br />detection limits approaching standards for four heavy metals: cadmium (Cd), <br />mercury (Hg), molybdenum (Mo) and copper (Cu). <br />Table 1 <br />Comparison of Applicable Receiving Stream Standards with Detection Levels <br />Element <br />Standard <br />(ppm) <br />Detection Limit <br />(PPm) <br />Cd 0.001 0.005 <br />Hg 0.00005 0.002 <br />Mo 0.01 0.2 <br />Cu 0.01 0.2 <br />CYCC should ascertain whether their equipment is adequate to attain detection <br />levels lower than the standards or contract with a laboratory which can <br />analyze the lower concentrations. The Division would like documentation of <br />these efforts to improve detection levels by May 15, 1986. <br />Data Formatti <br />The Division has made recommendations on formatting data in their evaluation <br />of the Eckman Park AHR. They are reproduced here as the Mine No. 3 and Eckman <br />Park AHR were formatted essentially the same. <br />1) A small scale map showing the location of all sampling sites is <br />requested. The large scale maps accompanying the report are often too <br />vague for us to identify whether a site is upstream or downstream of a <br />man-made structure, or on what side of the stream an alluvial well is <br />placed. <br />2) It would be helpful if you correlated SDP numbers (outfall 00X) <br />with site numbers. <br />