|
MATERfAL SAFETY DATA SHEET
<br />Days ro heat 1
<br />Primary Irdtation Index (PII): 0.4/8.0 .
<br />Omer egec#: None.
<br />Essentlaly non inflating.
<br />FIFRA category N.
<br />initatlon
<br />Rabbit, 6 animals, OECD 405 test:
<br />Days ro heal: 10
<br />Moderate initatlon.
<br />FIFRA category II.
<br />Skin sensitization
<br />Guinea pig, Buehler test:
<br />Positlve incidence: 0 %
<br />EXPERIENCE WITH HUMAN EXPOSURE
<br />Ingestion. short term, case re o s
<br />Gastro-intestinal effects: irritaCwn, nauseaNomding,
<br />dianhea
<br />Ingestion. sho term.:
<br />Respiratory effeds; increased fluid in lungs
<br />(lunglpulmonary oedema)
<br />Canfiovascular effects: decreased blood presswe
<br />(hypotension)
<br />Sim tar formulation
<br />Acute ora toxi
<br />Rao LD50: 5,000 mgMg body weigh
<br />SAghty toxk.
<br />FIFRA category III.
<br />Acute dermal t xic
<br />Rabbh, LD50 (limit test): > 5,000 nxykg body weight
<br />Practlca6y non-toxk.
<br />FIFRA category N.
<br />No mona0ty.
<br />Skin Inimtion
<br />Rab6h, 6 animals, OECD 404 fast:
<br />Days to heal: 3
<br />Pdmary IrdlaOon Index (PII): 1.018.0
<br />Srght irritation. '
<br />FIFRA category IV.
<br />Ewe Imitation
<br />RabblL 6 animals ,OECD 405 teat:
<br />Days b heat > 27
<br />Other aReds: pannus, tissue desWdbn in eye (necro-
<br />sfs of conjunciNae)
<br />Severe IrtilaBon,
<br />FIFRA category 1.
<br />Acute inhalation toxid
<br />Rat, LC50, 4 hours, aerosol: 328 mglL
<br />Prdctka0y non-toxk.
<br />FIFRA category IV.
<br />Skin sensitization
<br />Guinea pig, tNnduction Buehler test:
<br />Positive incidence: 0 %
<br />F~(PERIENCE WITH HUMAN EXPOSURE
<br />Ingestion. excessive intentional misusg'
<br />Respiratory effects: pneumoMiis (aspiration)
<br />Gastro-intestinal effects: nausea/vomiling, darrhea.
<br />abdominal pain, bbotly vaniting (haemalemesis)
<br />Cardiovascular effects: abnomal heart rhymm (car-
<br />diac dysrtymmla), tleceased heart outpN (myocardial
<br />depression)
<br />GeneraUSystemic effects: disturbances of fluid and
<br />electrolyte regulatbn, abnortnaM decreasetl bbod vo4
<br />ume (hypovolaemia), elevated serum amylase, flub
<br />toss (haemoconcenhabonj, no crx>6riesterese Inhibi-
<br />tion
<br />Laboratory effects -blood chemistry: elevatetl
<br />serum transaminases, mild acidosis
<br />Eyg confect short eon eofdemloloa'cal: I,
<br />Note: No pses of irreversible eye effects could be
<br />aanbuted ro gyphosate formubtbns in an extensive
<br />epidemblogkal survey d reported aceftlenml eye con-
<br />tact with these formula0ons.
<br />N-lahosohonomethvllalvcine: {glyohosate}
<br />Mutagenichv
<br />In vitro and in vNo mutagenidty test(s):
<br />Not mutagenic.
<br />R ate dose oxici
<br />Rabbit, dermal, 21 days:
<br />NOAEL tozkiry: > 5,000 mglk9 body weighUday
<br />Target organs/systems: None.
<br />Other effects: None.
<br />Rat, oral, 3 months:
<br />NOAEL toxicity: > 20,000 mg/kg diet
<br />Target organs/systems: None.
<br />Omer effects: None.
<br />UPDATES AVAILABLE AT WWW.GREENBOOK.NET
<br />CarclnogenidN
<br />Mouse, orel, 24 months:
<br />NOEL Nnwur: > 30,000 mg/kg diet
<br />NOAEL toxicity:.-. 5,000 mg/kg diet
<br />Tumours: None.
<br />Target orgarWsystems: river
<br />Other effects: decrease d body weight gain,
<br />histopadwbgic eReds
<br />Rat, oral, 24 months:
<br />NOEL tumour: > 20,000 mg4rg diet
<br />NOAEL roxfdry; ~. 8,000 mglkg diet
<br />Tumours: None.
<br />Target organslsystems: eyes
<br />Other effects: decrease of body weigh gain.
<br />histopattglogk eReds
<br />Toxic L raprodudionlfertiliN
<br />Rat, oral, 3 generations:
<br />NOAEL toxcity: > 30 mglkg body we1gM
<br />NOAEL reproduc5on; > 30 mgrk9 body weigh
<br />Target organs/systems in parents: None.
<br />Omer effects in parerns: None. -
<br />Target organs/systems In pups: Nona.
<br />Omer efteds in pups: None.
<br />Develoomental toxklNtteratoaenickv
<br />Rat. oral, 6 -18 days of gestation:
<br />NOAEL toxidy; 1,000 mglkg body wak]ht
<br />NOAEL devebpment 1,000 mg/kg body weight
<br />Other eReds in momer animal: decrease of body
<br />wegM gam, decease of survNal
<br />Developnrental effects: weigh loss, post-implantation
<br />loss, debyed ossifxation
<br />ERects on oRSpdng Doty observed with maternal tarF
<br />city.
<br />RabblL oral, 6 - 27 tlays of gestation:
<br />NOAF1 lozkity: 175 mg/kg boot' weight
<br />NOAEL devebpment 175 nxykg borty weight
<br />Target organslsystems m mother animal: None.
<br />Omer effects in motlrer animal: decease or survNal
<br />Devebpmenfal eReds: Npne.
<br />12. ECOLOGICAL INFORMATION
<br />This section S intended for use by eanoxicobgLsR and
<br />Diner erninonmental specialists.
<br />Monsanto has not conducted ernirgnmeMal studies
<br />on rata product Data obtained on simiWr products are
<br />summartred below.
<br />i ila formulation
<br />Aguatic xic sh
<br />Bluegill sunflah (Caporals maeroehirus);
<br />Acute tozkity, 96 hours, flowlhrough, LC50: 5.8 mglL
<br />moderetey rozk
<br />Rainbow trout (Ortcomynchus mykiss):
<br />Acute roxktty, 96 hours, flawlhrough, LC50: 8.2 ng4.
<br />motleretety toxk
<br />A atic oxl Invertebrates
<br />Water flea (Daphnia magna):
<br />Acute toxkiry, 48 hours, static, EC50: 12.9 mglL
<br />srgh0y toxk
<br />atic toxic algaelagua8c Ian
<br />Green algae (Selenastrum capdcomutum}:
<br />Acute tonicity, 96 txxlrs, stalk, EC50: 2.6 mg4_
<br />moderatey rozk
<br />Avian oxic
<br />Bobwhite quell (Colinas virginianus):
<br />Dietary toxkiry, 5 days, LC50: > 5,620 mglkg diet
<br />pradkaly non-toxk
<br />Mallard duck (Anal plarymynchos):
<br />Dietary toxidry, 5 days, LC50: > 5,620 mg/kg tliet
<br />pradiwly norvtozic
<br />ARhroood oxi'
<br />Honey bee (ADCs rttellifero):
<br />OreVcontad. 48 hours, LD50: > 700 pglbee
<br />pradkaly non-rozk
<br />Soil organism oxki invertebrates
<br />Earthworm (Elsenia foetida):
<br />Aside toxicky, 14 days, LC50: > 5,000 mg4cg dry Boll
<br />pmcticaly norFtoxk
<br />N-fohosohonomefhvllalvcine~ {glvohosate}
<br />Bfoaccumulatfon
<br />Bluegill sunfish (Caporals macrxhirus):
<br />Whole fish: BCF: < 1
<br />No signMwnt bioaccumulation is expectetl.
<br />Dlssioatlon
<br />Soil, field: ~!
<br />HaM life: 2 - 774 days
<br />Databas¢ and format copyright ®by C&P Press. All rtgh[s reserved.
<br />Koc: 864 - 60,000 Ukg
<br />Binds strongly to so0.
<br />Water, aerobic.
<br />HaV life: < 7 days
<br />Identical rod wltho gratin d~a
<br />Biotlearadation
<br />Zahn-Wellens fast:
<br />Degradation: 80 % wimin 2B days
<br />IMrerenlty biodegredable.
<br />13. DISPOSAL CONSIDERATIONS
<br />Product
<br />Dispose of as hazartlous industrial waste.
<br />Recyde 8 appropriate (ac0ides/equipmeM evallable.
<br />Bum in special, controlled high temperature incinera-
<br />ror.
<br />Keep out of drains, sewers, ditches ant water ways.
<br />Folow aA IocaUregionaUnational reguations.
<br />Container ,
<br />Tdple rinse empty containers.
<br />Pour dose water inb spiny tank.
<br />Stare for co0edbn DY approved waste disposal ser-
<br />vice.
<br />Dspose of as hazartlous ldustdal waste.
<br />Dg NOT re-use wntainers.
<br />Fdbw aE bcagregbneVnafional reguWibns.
<br />14. TRANSPORT INFORMATION
<br />The data provided in rata section a for informaton Doty.
<br />Please appy the appropriate regulations to propedy
<br />dassity your shipment for transpormtbn.
<br />Nd hazaroous under the applkebfe DOT, ICAOMTA
<br />IMO, TDG and Mexican regulatons.
<br />15. REGULATORY INFORMA710N
<br />TSCA Inventory ,
<br />All components are on the US EPA's TSCA Irnemory
<br />SARA Tida 111 Rules
<br />Section 311(412 Hazard Categories
<br />Immediate
<br />Section 302 Exfremey Hazardous Substances
<br />Nd applicable.
<br />Section 313 7oxk Chemical(s)
<br />Not applicable. ~
<br />CERCLA Reportable quandry
<br />Not aDPliwDk.
<br />16. OTHER INFORMATION
<br />The information given here k not necessady ezhaus-
<br />WB bur is repnzseMativeW relevam, reliable data.
<br />For more informaton refer to product label.
<br />Please consult MonsaMp 8 further informadon b
<br />needed.
<br />Follow all locaVregionaVnatlorml regulatons.
<br />In this tlocumeM me &ilish spelling was applied.
<br />All trademarks herein ere trademarks of Monsanto
<br />Company c fls subsitlianes.
<br />Full tlenominatbn d most frequently usetl acronyms.
<br />BCF (Bbconcentralign Factor), PAD (Bkchemkal
<br />Oxygen Demand), COD (Chem'mal Oxygen Dement).
<br />EC50 (50% ailed concentra8on), ED50 (50% effect
<br />dose). I,M. (intramuscular), I.P. ('mDaperikneel), I.V.
<br />(intravenous), ICoc (Sal atlsorptbn coeftident), LCSD
<br />tlase), LDLO (Lower Bma of Iemai dosage), LEL (Lower
<br />Expbsion Limit), LOAEC (Lowest Observed Adverse
<br />Effect Concentrafion), LOAF1 (Lowest ODServed Ad-
<br />verse ERed Level), LOEG (Lowest Observed Effect
<br />Concentration), LOEL (Lowest Observed ERed Levey.
<br />MEL (Maximum Exposure limit), MTD (Maximum Tol-
<br />erated Dose), NOAEC (No Observed Adverse Eflacl
<br />Concentratlon), NOAEL (NO Observed Atlverse Er-
<br />red Levey, NOEC (NO Observed ERed Concerttra-
<br />eon), NOEL (No Observed ERed Level), OEL (Occu-
<br />pational Exposure Limk), PEL (Permissible Exposure
<br />Limfl), PII (Primary Inflation Index), Pow (PaNOOn co-
<br />eifldeM n-octanoUwater), 6.C. (subcutaneous), STEL
<br />(Short-Term Exposure Umk), TLV-C (Threshold L'unR
<br />Value-Ceiling), TLV-TWA (Threshold Limit Value -Tune
<br />Weighted Average), UEL (Upper Expbsion Limkj
<br />This Material Safety Data Sheet (MSDS) serves dV-
<br />ferent purposes man arz! DOES~NOT REPLACE OR
<br />MODIFY THE EPA-APPROVED PRODUCT LABEL-
<br />ING {attached to and accompanying me produM wn-
<br />tainer). This MSDS provitles 'unportaM health, safety,
<br />Powered by C&P Press.
<br />-i
<br />
|