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MATERIAL SAFETY DATA SHEET
<br />UPDATES AVAILABLE AT WWW.GREENBOOK.NET
<br />ROUNDUP
<br />RIGINALT""
<br />erbicide
<br />Version: 1.2
<br />Effective date: 0125/2001
<br />1. PRODUCT AND COMPANY IDENTIFICATION
<br />Product name: ROUNDUP ORIGINAL''' Herbicitle
<br />EPA Reg. No.: 524-445
<br />Product use: laerbicMe
<br />Chemical name: Not applicable
<br />Synonyms: None
<br />Company
<br />MONSAN70 Company, H00 N. Lindbergh Blvd., St.
<br />Louis, MO, 63167
<br />Telephone: 800.332-3111, Fax: 31494-5557
<br />Emergency numbers
<br />FOR CHEMICAL EMERGENCY, SPILL, LEAK FIRE,
<br />EXPOSURE. OR ACCIDENT Call CHEMTREC -Day
<br />or NighT. 1-600<24-9300 toll free m the continental
<br />U:S., Puerto Rico, Canada, or Virgin Islands. For calla
<br />originating elsewhere: 703-52)-3687 {collect calls ac-
<br />cepted).
<br />FOR MEDICAL EMERGENCY -Day or Night 314-
<br />694-0000 (collect caAS accepted).
<br />Z. COMPOSRIONflNFORMA710N ON INGREDI-
<br />ENTS
<br />Active ingredient: Isopropylamine sa0 of N-
<br />(phosphonomemyl)gtyclce; {ISOpropylamme sea of
<br />gyphosate}
<br />Composition
<br />CONPONEM I CAS No. Is
<br />s.a of I sasat-sx.o n
<br />suMdenl 161]91-262 i e
<br />( ware' I nazaes I s I
<br />cede secret composition.
<br />SHA Status: This product is hazardous according to
<br />me OSHA Hazard Communication Smntlard. 29 CFR
<br />1910.1200.
<br />3. HAZARDS IDENTIFICATION
<br />Emeroencv overview
<br />Appearance end otlaur (eolourNarModour): 1 Uq-
<br />uid / Slight -
<br />WARNING!
<br />Keep out of reach of children.
<br />CAUSES SUBSTANTIAL BUT TEMPORARY EYE IN-
<br />JURY
<br />HARMFUL IF SWALLOWED
<br />HARMFUL IF INHALED '
<br />REFORMULATION IS PROHIBITED
<br />SEE INDIVIDUAL CONTAINER LABEL FOR
<br />REPACKAGING LIMITATIONS
<br />Potential health eRects
<br />Likety routes of exposure: Skin contact, eye contact
<br />Eye contact, short term: Causes temporery eye imF
<br />tatlon.
<br />Skin contact, short term: Not expected fe prafuce
<br />significant atlverse eRects when recommended use
<br />InsWClions a2 folkrvetl.
<br />Inhalaton, short term: Not expected to produce sig-
<br />nifwanl adverse eRects when recommended use in-
<br />structions are followed.
<br />Refer to section 11 for toxiwbgiral and section 12 For
<br />environmental information
<br />4. FIRST AID MEASURES
<br />Eye contact
<br />Immediatery flush with pleny of water.
<br />Continue for at least 75 minutes.
<br />If easy to do, remove contact lenses.
<br />If there are persistem symptoms, obtain nredical ad-
<br />vice.
<br />Skin contact
<br />Wash aRected skin with plenty of wafer.
<br />4""r~-~~,~~ Wash clothes before re-use.
<br />yam" Take o0 contaminated cbthing, wristwatch, jewellery.
<br />Inhalation
<br />Remove to fresh air.
<br />Ingestion
<br />Immediatey o0er water b drink.
<br />Do NOT induce vomiting unless directed by medical
<br />personnel.
<br />If symptoms occur, get medical attention.
<br />Advice to doctors
<br />This product is not an inhibitor of cholinesterase.
<br />Antidote
<br />Treatment with atropine and oximes is not intlicated.
<br />5. FIRE FIGHTING MEASURES
<br />Flash point
<br />Does not flash.
<br />Extinguishing metlia
<br />Rewmmendetl: Water, dry chemical, carbon dioxide
<br />(C02), foam
<br />Unusual fire and explosion hazards
<br />None.
<br />Environmemal precautbns: see section 6.
<br />Hazardous products of combustion
<br />Carbon morwxide (CO), nitrogen oxides (NOx), phos-
<br />phorus oxides (PxOy)
<br />Fire RghOng equipment
<br />Se0-contained breaming apparatus.
<br />Equipment shoub he thoroughly tlecomaminated after
<br />use,
<br />6. ACCIDENTAL RELEASE MEASURES
<br />Personal precautions
<br />Use personal protection recommended in section e.
<br />Environmental prerauticns
<br />SMALL QUANTRIFS:
<br />Low environmental hazard.
<br />LARGE OUANTTfIES:
<br />Minimae spread.
<br />Keep out of drains, sewers, ditches and water ways.
<br />Methods for cleanln8 up
<br />SMALL QUANTITIES:
<br />Flush sptil area wHh water.
<br />LARGE QUANTTfIES:
<br />Absorb m earth, sand w absorbent material
<br />Dig W heaviy wniaminated soA.
<br />Collect in containers iw tlisposal.
<br />Refer to section 7 for tYPes of containers.
<br />F1usA residues with small quantities of water.
<br />Minimae use of water to prevem envzonmental con-
<br />taminagon.
<br />Refer to section 13 for disposal of ap0led material.
<br />7. HANDLING AND STORAGE
<br />Handling
<br />Good industdal practice kt housekeeping and personal
<br />hygiene should be followed.
<br />Avoid contact Wtth skin antl eyes.
<br />When using do not eat, tldnk or smoke.
<br />Wash hands moroughy after hantlGng or contact.
<br />Thoroughy clean equipment after use.
<br />Emptied wnlainers retain vapour and produc(residue.
<br />Observe all labelled safeguards until <onginer is
<br />cleaned, reconditioned or destroyetl.
<br />Emptied containers retain vaDOUr and product residue.
<br />FOLLOW LABELED WARNINGS EVEN AFTER CON-
<br />TAINER IS EMPTIED.
<br />Storege
<br />Compatible materials for slorege: stainless steel, alu-
<br />minium. Dlastic, fibreglass, glass lining
<br />IncomDatltb matedals for storage; galvanised steel,
<br />unlinetl mild steel, see section 10.
<br />Keep ou[ of reach of dhilden.
<br />Keep away from food, drink and animal feed.
<br />Keep Dory in me original wntainer.
<br />Panial crystallization may occur on probnged storage
<br />oeiow the minimum Stomge temperature.
<br />f frozen, place in wane room and shake frequemy to
<br />Sul back into solution.
<br />Minimum shaft life: 5 years.
<br />S. EXPOSURE CONTROLS/PERSONAL PROTEC-
<br />r10N
<br />lirbome exposure limits
<br />Database antl forma[ copyright ©by C8P Press. All rights reserved.
<br />
<br />Cpmponsnts Expasun GUleegnss
<br />Wpropylamna un Np NatlRC Orapaaw,sl exposure anb
<br />orglyphosate has been eaNbashad.
<br />Surbtlanr No spatlbc pcapaam,al exposure box
<br /> hea been umbtlshed.
<br />WaM No epadbc oavpabnal exposure tlmg
<br /> M, bem eWbtahed.
<br />Engineedng controls
<br />Have eye wash (actlities immediatery available at lo-
<br />catbns where eye contact can occur.
<br />Eye protection
<br />If Mere is potential for comact
<br />Wear chemical goggles.
<br />Skin protection
<br />It repeated w Drobnged contact
<br />Wear chemcal resistant gbves.
<br />Respiratory protection
<br />No special requiremem when usetl as recommended.
<br />When rewmmendetl, wnsutt manufacturer of per-
<br />sonal protective equipment for the appropriate ype
<br />of equipmem for a given application.
<br />9. PHYSICAL AND CHEMICAL PROPERTIES
<br />These physical data are typical values based on mate-
<br />dal tested but may vary from sample to sample. Typ-
<br />ical values should cwt be wnsinred as a guaranteed
<br />analysis of any specific bf w as spec}6cations tw the
<br />product
<br />Fgnn: ugwd
<br />Otlpur. alight
<br />Rash polite Uoas rKK Dash.
<br />apedficgmviy. 7.1655 ~ 20'G15.6'C
<br />pH: x.43.0
<br />PBNSm oxfidant
<br />(109 Powy G 0.000 (ectlva irgredienq
<br />10. STABILfTY AND REACTMTY
<br />Stability
<br />Stable untler nomx9l wnditlons of hantl6ng and siw-
<br />age.
<br />Hazardous dewmposition
<br />Themral decomposition: No tlata.
<br />Hazardous products of combustbn: see section 5.
<br />Materials to avoidlReactivity
<br />Reacts with bases b liberete heat
<br />Reacts with galvanised steel or unlined mild steel b
<br />produce hytlrogen, a highy flammable gas that could
<br />explode.
<br />Hazardous polymerization
<br />Dces not occur.
<br />11. TOXICOLOGICAL INFORMATION
<br />This segbn is Intended for use by toxiwlogists antl
<br />Omer heetth professionals.
<br />Data obtained on product or on sunilar products are
<br />summarized bebw, Data obtained on active ingredient
<br />are sumrreraed below.
<br />Acute ol~a oxicf
<br />Rat, LD60 (limit test): > 5,000 mglkg body weight
<br />Other eflecrs: breamirg dificul y, decreased actMy,
<br />soft Stools
<br />PracOcaly non-toxic.
<br />FIFRA category IV,
<br />No mortality.
<br />Acute dermal fox ei
<br />Rat, LO50 (limit test): > 5,000 mg/kg body welgn[
<br />Target organslsystems: None.
<br />Omer effects: None.
<br />Practicaly non-toxic.
<br />FIFRA category IV.
<br />No mortality.
<br />Acute nhalation oxicf
<br />Ral, LC50, 4 hours, aerosol: 2.6 mg/L
<br />target organs/systems: None.
<br />Diner effects: breathing dilficulry, decreased acfwiy,
<br />local e0ecis
<br />orectically non-toxic.
<br />PIFRA category IV.
<br />Skin imitating
<br />Rabbit, 6 animals, OECD 4p4 test:
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