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C-PIT Hydrogeologic Investigations <br />Technical Revision No. 8 <br />3: Observations and Results Mining Permit M-1977-208 <br />Although a single water sample was obtained From compliance well CEM-005, the results shown on Table 2 <br />are not considered to be representative of formation water. This water is presumed to be residual water from <br />the well drilling process. <br />3.3 Boulder Feeder Canal Gauging Results <br />Brown and Caldwell conducted two flow measurements on the reach of the Boulder Feeder Canal located to <br />the west of the C-Pit Site on July 19, 2007. No quantification of seepage losses from the canal could be made <br />from this exercise. <br />The stream gauging calculations indicate the flow rate at the upstream measurement station was 86.2 CFS, <br />and flow at the downstream station was calculated to be at 88.1 CFS. The difference in these values is <br />approximately 2 percent, which is within the range of expected accuracy for the methods employed. The <br />operator of the ditch, NCWCD, reported the flow rate at the 10-foot flume located on the canal upstream of <br />C-Pit and immediately east of Highway 36 (Foothills Parkway) was 89 CFS at the time of gauging. <br />3.4 Compliance Well CEM-005 <br />It is Brown and Caldwell's opinion that the most recent fieldwork conEtrms that the water currently in <br />CEM-005 is likely residual water remaining from the drilling process and draining from the surrounding sand <br />pack. Although a sample was obtained from CEM-005 in May 2005, there is no apparent hydraulic <br />connection between C-Pit and well CEM-005. The water elevation in C-Pit and potentiometric level in <br />monitoring well CEM-001 axe approximately 390 feet higher than the measured water elevation in CEM-005. <br />CEMEX continues to monitor the water level in CEM-005 to conEtrm the existing information. <br />3.5 Geochemical Evaluation <br />Stiff diagrams and Piper plots were prepared from the available surface and groundwater chemisny data for <br />C-Pit, the monitoring wells, piezometex P-003 and the Boulder Feeder Canal Figures 10 and 11 display the <br />plotted data. <br />The ground and surface water geochemistry signatures of alluvial well CEM-004 and the Boulder Feeder <br />Canal appear to be tin-impacted, and likely represent meteoric water or water with very little contact time with <br />rocks in the area. This is evident by the low total dissolved solids (TDS) relative to the other samples. <br />The six water samples each plot as different water types, indicating a relatively isolated and discontinuous <br />groundwater flow system fox this Site: <br />1. CEM-004 (the alluvial well northeast of C-Pit) is a calcium bicarbonate water type. <br />2. The Boulder Feed Canal is a calcium bicarbonate water type. <br />3. C-Pit water is asodium-potassium sulfate water type. <br />4. CEM-001 water is asodium-potassium chloride water type. <br />5. CEM-003 is asodium-potassium bicarbonate water type. <br />6. P-003 is a calcium sulfate water type. <br />Although a hydraulic connection exists between C-Pit and monitoring well CEM-001 to the east, the <br />geochemical signatures of the water at these two locations are signiEcandy different Moreover, the C-Pit <br />geochemical signature changed over time following the placement of fill into the pit beginning in March 2007. <br />The pH of the pit water shifted from approximately 12.3 to 8.0 (su) during this period, and calcium, sodium, <br />3-3 <br />Use of contens on Ihis sheet rs subled to the limitations specdiad at the end of this document <br />\\BCDEN02\pro~eclslDalalGEN\Gemex\TR-8\RepoNng\CEMEX Repor108-31-07.doc <br />