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COLORADO DEPARTkfENT OF HEALTH. Water Quu/iry Control Division <br />Rationale - Pnge l3, Permit No. CO-0034/42 <br />Table V/-6 -- Summary ofMass Balance Calculations (out(alls 003, 022 and 014) <br />Parameter Stream Standard, (M3), Effluent Conaentration, (M2J, <br />AculdChronic AcutdChronic <br />Arsenic (T), pg/u 50% 373/- <br />Cndmiunr (PO), NS/~ ?5.75/1.31 /99//9 <br />Copper (PDJ, pg/~ 39.51/24.45 305/2/3 <br />Iron (TRJ, pg/~ -/1000 -/1000• <br />Iron (PD), pg/i7 -/300 -/300' <br />Lead (PD), pg/~7 378.29/12.98 Z92d///3 <br />Manganese (TR), pg/~ _/1000 -/R153 <br />Manganese IPD), pg/0 -/50 -/434 <br />hlercury (T), pg/~7 -/0.0/ -/0.09 <br />Nickel (PD). pg/~7 1765.24/182.37 136x7/1585 <br />Silver (PD), pg/u 8.79/1.33 68/12 <br />Zinc (PD), pg/~ 240.49/217.83 /859//893 <br />T= Total. PD= Patentinlly Di.rcalved. TR=Total Recavernhlejrnction.c <br />' Because the ambient concentration is greater than the WQ.rtandurd, the lirnitatian equals the.rtnndnrd. <br />To[ul Residual Chlorine lout(u(l 0231: Water quu(iN-bused e(f<uen[ limitations fur to(nl residual cldorine, were <br />calculated rat outfnll 023 bused upon n design capacity oj0.0/2 MGD (0.0/9 cftJ. A![lrough the previous permit <br />rationale irtdica[ed that the wastewater Jloty will increase ro 0.022 MGD within S to 10 cearr, t{+e reported flow <br />vulaes in Table V-l indicule that the efJluemflow.r /rave not exceeded 0.0/2 MGD. Therefore, effluent lirnitntimr.t' <br />will he calculnter/rat om[jnll 013 braced on n marimurn flow oj0.012 MGD. Since tiro discharge conci.rts a(domestic <br />x'nctewwter. no odnrr pollutuntc except pH, are expected ro be present in dre dlrerinrge. The enlculaled effluent <br />limilalion for tom/ residual chlorine is greater than that allowed by the State Regvlnkon.c for Effluent Lirnitntion.r. <br />Therefore the limit oj0.5 mg/~ (daily maximum) speclfred in the Regulotions shn// apply. <br />Toml Ammonia /out(nll 023): Forlorn/ ammonia, the default maximum allowable in.rlr'earn concenlrntion.r listed in <br />.reckon 111.,4.3. were used in con.riderntion ojthe need jar tan! ammonia limitations. The mast restrictive ins(ream <br />standard shown in Table l!I-2 is !. I mg/~~ jar September and October. Using (hrs s[atdard in the mass balance <br />enlculntion results in a lirnitaion oj2,780 mg/~ -much greater than any concen.!ration erpecred to be found in the <br />effluent. Therejor'e. no limitation or monitoring jar ammonia will be reyair'ed. <br />Memlc (out(nlLc 003. 022. 024): For mctnlr with dirrolved.ctnndnrdr, corresponding effluent limilr are based upon <br />the potentially rli.csolved method ojunulvsi.r. For smndurdr bused upon the total and total recoverable methods of <br />nnnlyci.r, the limits are based upon the same method nr the .standard. except for nr.renic. For arsenic. the mtnl <br />recoverable nnulysi.r must he performed using n grnphue jur'nuce. <br />/n the event dre background concentration war reported a.r lolnl recoverable rand (he most stringent criteria was <br />bored on the potentially dicrolved method ojnnnlvri.r, background concenvntion.c were assumed to be zero. <br />Similarly, ijthe 6nckground concemtrnrion was reported ar porentin(!y dissolred and the roost stringent criteria rrns <br />based on u torn/ recoverable medrad of nnnlvci.r, bnckgrowrd concentralion.c wera ul.ro n.r.cumed to he zero. Table <br />V/-h /isrc the maximum efJlaenr corrcenrration of pollutants that could he di.cchun;ed from Outjnllr (J03, 022, rand <br />024. <br />