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HYDRO20043
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HYDRO20043
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Last modified
8/24/2016 8:41:28 PM
Creation date
11/20/2007 1:20:16 PM
Metadata
Fields
Template:
DRMS Permit Index
Permit No
C1981033
IBM Index Class Name
Hydrology
Doc Date
2/25/1998
Doc Name
WEST ELK GEOCHEMICAL ASSESSMENT OBSERVATIONS AND INTERPRETATIONS
From
HARRY POSEY
To
DAVE BERRY
Permit Index Doc Type
OTHER SURFACE WATER
Media Type
D
Archive
No
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Snow and rain infiltrate rocks upgradient ofthe NW Panels sealed sump. As <br />these waters travel through the rock mass, soluble constituents enter the water. As these <br />meteoric waters containing dissolved solids mix with the fault waters in the sump, the <br />sump water changes in composition. <br />The addition of Ca and Mg might be explained by the dissolution of dolomite -- <br />(CaMg)CO;. If dolomite was dissolved, the incoming fluid containing it should also <br />contain an equivalent (more-or-less) amount of bicarbonate. The seep water contains a <br />lower amount of bicarbonate than the fault, but more than enough to balance the Ca and <br />Mg from dolomite dissolution. Therefore, it is feasible that the incoming meteoric water <br />contained Ca, Mg and bicazbonate, but the bicarbonate was lower in that fluid than the <br />fault waters, so the net effect was to lower bicarbonate in the mixture. <br />The fault waters are chazacterized as sodium bicarbonate waters whereas the seep <br />waters are sodium potassium calcium bicarbonate sulfate waters. The same meteoric <br />water [hat contained dissolved dolomite could also contain dissolved potassium and <br />sodium, both of which aze probably readily available in local Cretaceous rocks. The <br />relative increase in K (from about 3 mg/L in the fault water to 8 in the seep water) would <br />indicate that the meteoric water contained the higher K content. The minor, if any, <br />decrease in Na likewise can be attributed to the relative concentrations of Na in the fault <br />waters and the meteoric water, the meteoric water having the lower concentration. <br />The introduction of meteoric water could also explain the drop in pH. Meteoric <br />water has a typical pH in the range of ~.5 - 6.5 (see for instance, A.W. Hounslow, 199, <br />Water Quality Data, Analysis and Interpretation, CRC/Lewis Publishers, New York, p. <br />169). The Edwards Portal seep has a pH of 6.79 compared with pH values in excess of 8 <br />for the fault waters. Easily, dilution of [he fault waters by rain or snow could explain this <br />shift, and as noted above, meteoric water mixing is consistent with several findings. <br />Isotope geochemistry. <br />At first glance, an increase in sulfate in the water Wright indicate gypsum (or <br />anhydrite) dissolution. However two points argue against gypsum as a source. First, <br />there is not enough Ca to balance the sulfate, so that eliminates a gypsum source unless a <br />parallel mechanism is developed to remove Ca from solution. However, that approach <br />may be unnecessarily complex. The second point lies in the sulfur isotope composition <br />of the dissolved sulfate. The SJ4S values, which range up to +44.4 per mil, are up [0 15 <br />permit enriched over even the heaviest seawater sulfate. (Seawater is the source from <br />which most gypsum/anhydrite derives, especially in the Paleozoic and pre-Tertiary rocks <br />of this area which are dominantly marine in origin). Furthermore, the S'4S values are <br />about 25 permit enriched over late Cretaceous seawater, which arguably is the most likely <br />ultimate source of gypsum locally (see Holler and Kaplan, 1966, Chemical Geology, vol. <br />1, No. 2, p. 93-135). Thus, gypsum or anhydrite in the sedimentary column are not the <br />likely source of the sulfate in the Lone Pine seal and Edwards Portal seal waters. <br />As mentioned above, the enriched (isotopically heavy) S"S values of the sulfate <br />azgue for a source area where sulfate, possibly in [he presence of methane oxidation, has <br />undergone enrictunent due to the preferential reduction of sulfate containing the lighter <br />
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