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MATERIAL SAFETY DATA SHEET
<br />ROUNDUP
<br />~ORIGINALT""
<br />erbicide
<br />Version: 1.2
<br />Effective date: 01/252001
<br />1. PRODUCT ANO COMPANY IDENTIFICATION
<br />Protlucl name: ROUNDUP ORIGINAL]" Herbicide .
<br />EPA Reg. No.: 524145
<br />Product use: Herbicide '
<br />Chemical name: Not applicable
<br />Synonyms: Norre
<br />Company
<br />MONSANTO Company, 800 N. Lindbergh BNd., St.
<br />Louis, MO, 63167
<br />Telephone: 800-332-3117, Fax: 314694-5557
<br />Emergency numbers
<br />FOR CHEMICAL EMERGENCY, SPILL. LEAK FIRE,
<br />EXPOSURE, OR ACCIDENT Ca0 CHEMTREC -Day
<br />or Night 1-800124-9300 toll free in me conOnental
<br />U:S., Puerto Rico, Canada, or Virginlslands. Far calls
<br />originating elsewhere: 703-527-3887 (colleq calls ac-
<br />cepted).
<br />FOR MEDICAL EMERGENCY -Day or Night 314
<br />6941000 (colleen caAS accepted).
<br />T. COMPOSITION/INFORMATION ON INGREDI•
<br />ENTS
<br />Active ingredient: IsoDropylamine caa of N-
<br />(phosphonomemyl~ycine; {IsoproDYlamine sect of
<br />gyp/asate}
<br />Composition
<br />COMPONENT '- C>a Ne. I tai
<br />I laopmpyromna a,n or I sasat-sao I at I
<br />Sudetlanl 61]91-2&2 a
<br />Wahl ~ ]]31483 61
<br />rode secret composition.
<br />SHA Status: This product is hazardous accordng to
<br />the OSHA Hazartl Communication StarMarQ 29 CFR
<br />1910.1200.
<br />3. HAZARDS IDENTIFICATION
<br />Emergencv overview
<br />Appearance and odour (colourROrm/odour): / L'p-
<br />uid / SIigM
<br />WARNINGI .
<br />Keep out of reach of children.
<br />CAUSES SUBSTAMIAL BUT TEMPORARY LYE IN-
<br />JURY
<br />IiARMFUL IF SWALLOWED
<br />HARMFUL IF INHALED
<br />REFORMULATION IS PROHIBITED
<br />SEE INDIVIDUAL CONTAINER LABEL FOR
<br />REPACKAGING LIMITATIONS
<br />Potential heahh effects
<br />Likely routes of exposure: Skin contact, eye contact
<br />Eye contact, short term: Causes temporary eye intl.
<br />ration.
<br />Skin contact, short term: Not expected to produce
<br />significant adverse effects when rewmmended use
<br />insirucfions are followed.
<br />inhalation, short term: Not expected tq produce sig-
<br />nificant adverse effects when recommended use in-
<br />structions are followetl.
<br />Refer to section 11 for toxiiobgical and section 12 for
<br />environmental information '
<br />4. FIRST AID MEASURES
<br />Eye contact
<br />Immediately flush with plenty of water.
<br />ConOnue for at least 15 minutes.
<br />If easy to tlo, remove contact lenses.
<br />If there are persistent symptoms, obtain medical ab
<br />vice.
<br />Skin contact
<br />Wash aAected skin wan plenty of wafer.
<br />Wash cbthes before re-use.
<br />Take oft contaminated clothing, wristwatch, jewellery.
<br />Inhalation
<br />UPDATES AVAILABLE AT WWW.GREENBOOK.NET
<br />Remove to fresh ale.
<br />Ingestion
<br />Immediately offer water to drink.
<br />Do NOT induce vomaing unless directed by medical
<br />personnel.
<br />If symptoms occw, get medical attention.
<br />Atlvica to doctor
<br />This product is not an inhibitor of cholinesterase.
<br />Antidote
<br />Treatment with atropine and oximes i5 not indicated.
<br />5. FIRE FIGHTING MEASURES
<br />Flash point
<br />Dces not flash.
<br />Eztingufshing media
<br />Recommentletl: Water, tlry chemical, carbon dioxide
<br />(C02), foam
<br />Uhusual Rre and explos(on hazards
<br />None.
<br />Environmerdal prewWions: see section 6.
<br />Hazardous products of combustion
<br />Carbon monoxide (CO), nitrogen oxides (NOx), phos-
<br />phorus oxides (PxOy)
<br />Fire fighting equipment
<br />Sea-contained breathing apparatus.
<br />Equipment should be thoroughy tlewntaminated after
<br />use.
<br />
<br />CemponanU EipOSVre GUMalroes
<br />IsoPmDNamFa uX No yredic ocapanonel azpowre fmn
<br />M 9NVhosaro nn aeen esroaHnee.
<br />aurfatleM fao gnwtc awpetlanal0xpuure anti
<br /> ma aeon aamntsnae.
<br />W afar Ho apednc ompatbnal exposure Mma
<br /> Iwo aun esuafan.a.
<br />Engineering conlrok
<br />Have eye wash facailies immediatey available at lo-'
<br />catipns WFlefe Gy¢ LOnteci Can OLCIa,
<br />Eye protection
<br />It there is potential for contact
<br />Wear chemical 9o99ks.
<br />Skin protection
<br />H repeated w proonged confect
<br />Wear chemical res'ataM gloves.
<br />Respiratory protection
<br />No special requirement when used as recommended.
<br />When recommended, consua manufacturer of per-
<br />sonal protectNe equipment for the appropdate type
<br />of equipment fora given aDDI'aation.
<br />9. PHYSICAL AND CHEMICAL PROPERTIES
<br />These physical data are typical values basetl an rtfate-
<br />rial tested DN may very hom sample to sample. Typ-
<br />ical values should rat ce conttnned as a guaranteed
<br />anaysis of arty specific bl w as specificafbns for the
<br />product
<br />6. ACCIDENTAL RELEASE MFASURES~
<br />Personal precautions
<br />Use personal protection recommended a secon 8.
<br />Environmental precautions
<br />SMALL QUANT771ES:
<br />Low enwironmental hazard.
<br />LARGE QUANTITIES:
<br />Minimize spread. '
<br />Keep out of drains, sewers, ditches and water ways.
<br />M¢thods for cleaning up
<br />SMALL QUANTITIES:
<br />Flush spBl area wdh water.
<br />LARGE QUANTITIES:
<br />Absorb in earth, saM or absorbent material.
<br />Dig up heaviy contaminated soil.
<br />Collect in wntainers for disposal.
<br />Refer to section 7 for types of containers.
<br />Flush residues with small quantities of water.
<br />Minimze use of water to prevent environmental cen-
<br />tamination.
<br />Refer to section 13 fa disposal d spilletl material.
<br />7. HANDLING ANb STORAGE
<br />Handling
<br />Good indusinal practice in housekeeping and personal
<br />hygiene sliouW ce folbwetl.
<br />Avow cenlad wah skin and dyes.
<br />When using tlo not eat, tlrtnk or smoke.
<br />Wash hands ihorougNy offer handling or confad.
<br />Thoroughy clean equipment aaer use.
<br />Emptied containers retain vapour and protludt resque.
<br />Observe all labelled safeguards un01 container~is
<br />cleaned, reWndaioned or destroyed.
<br />Emptied containers retain vapour and product resitlce.
<br />FOLLOW LABELED WARNINGS EVEN AFTER CON-
<br />TAINER IS EMPTIED.
<br />Srorage
<br />Compatible: matedals for storage: stainless steel, alu-
<br />minium, plastic, fibreglass, glass lining
<br />IncomDaable materia6 for storage: galvanised steel,
<br />unlinetl miltl steel, see section 10.
<br />Keep out of reach of children.
<br />Keep away from food, drink and animal feed.
<br />Keep Dory in ire orginal container.
<br />Partial crystallization may occur on prolonged storage
<br />bekrw me minimum storage temperature.
<br />If frozen, place in warts room and shake hequenty ro
<br />pW back into solution.
<br />Minimum shell life: 5 years.
<br />B. EXPOSURE CONTROLS/PERSONAL PROTEC- ~
<br />girbome exposure limits
<br />Database and format copyright ©by C8P Press. All rights reserved.
<br />t tti
<br />t ..,
<br />>.-.. +rHi~eh...saie... __s._
<br />Form: liquid
<br />Odour: Slgnt
<br />Flash pdM: Doan rot aaen.
<br />6nadaC gravity. 1.1655 Q 20'G15.6'C
<br />pH: x.46.0
<br />PaNOOn cceaidaM
<br />(log Pow): < 0.000 (active ingredient)
<br />10. S7ABILfTY AND REACTIYITy
<br />Stability
<br />Stable under mm~al corMilforts o/ haMlkfg and shx-
<br />a9e.
<br />Hazardous decomposition
<br />Thermal decampos0ion: No data.
<br />Hazardous products of combusgon: see section 5.
<br />Mafedals to avoid/ReaeHVity
<br />Reacts with bases to liberate heal
<br />Reacts wan gavanlsed steel a unlined mild steel a
<br />produce hydrogen, a highy flammable gas that could
<br />exPbde.
<br />Hazardous poymerization
<br />Dces not acwr.
<br />11, TO%ICOLOGICAL INFORMATION
<br />This sectbn is intended for use by toxicologisLS and
<br />other health professionals.
<br />Data ohtained on product or on similar protlucLS are
<br />summarized oebw. Data obtairletl on active ingredient
<br />are summarized below,
<br />Acute oral toxi I
<br />Ral, LD50 (limit test): > 5,000 mg/kg hotly wegM
<br />Other effects: breathing difficulty, decreased activity,
<br />so0 stools
<br />Pmcdcaly ran-[oxb.
<br />FIFRA category N.
<br />No mortally.
<br />Acute dermal toxic
<br />Rat, L~50 (IImK tesl~: > 5.000 mg/kg body wegM
<br />Target organs/systems: None.
<br />Other eNects: None,
<br />Practicaly non-toxb.
<br />FIFRA category N.
<br />No modality.
<br />Acute inhalation toxici
<br />Rat, LC50, 4 hours, aerosol: 2.6 mglL
<br />Target organs/systems: None.
<br />Omer effects: breathing tlificuay, decreasetl activay.
<br />local effects
<br />PracticeAy non-toxic.
<br />FIFRA category N.
<br />Skin Irritatio
<br />Rahbg, 6 animals, OECD 404 test:
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