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2021-06-23_REVISION - M1977300
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2021-06-23_REVISION - M1977300
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Last modified
1/11/2025 3:15:51 AM
Creation date
6/24/2021 7:06:57 AM
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Template:
DRMS Permit Index
Permit No
M1977300
IBM Index Class Name
REVISION
Doc Date
6/23/2021
Doc Name Note
*NO PAYMENT INCLUDED*
Doc Name
Request For Amendment To Permit
From
Colorado Legacy Land
To
DRMS
Type & Sequence
AM6
Email Name
AME
MAC
Media Type
D
Archive
No
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COLORADO LEGACY LAND <br /> $CHWARTZWALDER MINE <br /> a reducing environment is being achieved to form insoluble uranium species that precipitate out of the mine <br /> pool. <br /> As shown on Figure E-4, dissolved molybdenum concentrations indicate a consistent pattern of decreasing <br /> concentrations with the in-situ treatments followed by an increase in concentrations. The dissolved <br /> molybdenum concentrations decreased from approximately 1.5 mg/L before the first in-situ treatment in 2013 <br /> to a minimum of approximately 0.04 mg/L, an approximate 97% reduction in concentration. There was a <br /> rebound in dissolved molybdenum concentrations in 2014, which decreased again after the injections of <br /> MicroC®and molasses in 2015.The dissolved molybdenum concentrations again rebounded to a maximum of <br /> approximately 6 mg/L before the second in-situ treatment in 2017 followed by a decrease to a minimum of <br /> approximately 0.05 mg/L,an approximate 99%reduction in concentration,after which dissolved molybdenum <br /> concentrations started increasing.The decreasing dissolved molybdenum concentrations is another indication <br /> of a reducing environment. <br /> As shown on Figure EA the molybdenum concentrations increased in 2018 following the in-situ treatment in <br /> 2017, decreased after the in-situ treatment in 2020, and started to increase until the last sampling event in <br /> September 2020. The pattern of increasing and decreasing molybdenum concentrations with in-situ <br /> treatments is consistent. As shown on Figure E-3, there was not a significant decrease in uranium <br /> concentrations after the 2020 in-situ treatment as was seen in the previous in-situ treatments.There may be <br /> several factors for the absence of the significant decrease as follows: <br /> • The natural population of SRB in the mine pool might be at a steady-state condition from the 2017 <br /> in-situ treatment and not actively biocycling sulfur. <br /> • The mine pool uranium concentrations in 2020 were nearly the same as in 2018 and these <br /> concentrations may indicate that there was a rate limiting factor in the creation of a proper reducing <br /> environment conducive to the reduction of U(VI) to U(IV), combined with other factors discussed <br /> herein. <br /> • The addition of sump water to the mine pool during treatment may not have occurred at a regular <br /> frequency for the previous in-situ treatments, as indicated by available data. During the period the <br /> mine pool pump was off after the in-situ treatment began in January 2020 until the mine pool pump <br /> was turned on in April 2020, the sump water pumped into the mine an average of 5 gpm with a <br /> maximum during this period of approximately 18 gpm.Thus,oxygenated water was entering the mine <br /> pool and may have disrupted the creation of a sufficient reducing environment. <br /> A red circle is shown on Figures E-3 and E-4 to signify suspect data in the months preceding the 2017 in-situ <br /> treatment. These data are suspect because in the nearly 10 years of data shown on these figures, uranium <br /> concentrations have not exceeded 25 mg/L and molybdenum concentrations have not exceeded 2 mg/L,with <br /> the possible exception on one sampling event in November 2017. The sudden increase in uranium and <br /> molybdenum concentrations does not fit with historical data and there is no plausible explanation to the <br /> increase. However, while a definitive explanation is not available to rule out this anomaly, it is thought that <br /> there might have been either a mix-up in the labelling of the samples the samples were collected from the wrong <br /> sample port. For example, treated water, which has a higher concentration of uranium and molybdenum is <br /> returned to the mine pool. Mislabelling the return samples as raw mine pool samples is as plausible an <br /> explanation as collecting the return samples from the wrong sample port.Regardless,the suspect data do not <br /> alter the conclusion that the mine pool has been chemically stable for the last three years. <br /> JUNE 2021 20 AMENDMENT 6 <br />
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