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COLORADO LEGACY LAND <br /> $CHWARTZWALDER MINE <br /> E.S.2.2. In-Situ Treatments <br /> Prior to the in-situ treatment of the mine pool in 2020,there were three previous in-situ treatments in 2013, <br /> 2015,and 2017.These in-situ treatments are discussed in the following paragraphs. <br /> The initial in-situ mine pool treatment was completed in May 2013 as a pre-treatment step to the RO system in <br /> which molasses and methanol were injected into the mine pool.Molasses was injected in the#1 Shaft(-800 ft <br /> deep),the#2 Shaft(-1,160 ft deep),and the open hole behind the bulkhead.The injection location points are <br /> shown on Figure E-2. Three subsequent monthly injections of methanol followed, and a second injection of <br /> molasses and methanol was made six months after the start of treatment. <br /> The in-situ treatment was interrupted by a 1,000-year rainfall event in September 2013 that prohibited access <br /> to the Schwartzwalder Mine from September 2013 until the summer of 2015. Although truck access to the <br /> Schwartzwalder Mine was still limited in 2015 and a tanker could not make it to the site, totes of <br /> MicroC® (a carbon source)and molasses were brought to the Schwartzwalder Mine and injected into the mine <br /> pool in June and September,respectively. <br /> In December 2017, the in-situ treatment of the mine pool consisted of an injection of phosphoric acid and <br /> molasses into the#2 Shaft. The 25-hp pump was operating and the mine pool effluent was reinjected into the <br /> #2 Shaft after being processed through the RO units. The operation of the pump allowed for a mixing of the <br /> mine pool to distribute the molasses and phosphoric acid.The pump was shut down on December 22, 2017, <br /> and not restarted until January 15,2018. <br /> In December 2019,the 60-hp was turned off and was not restarted until April 2020.On January 28,2020,beet <br /> molasses,phosphoric acid,and the tracer Rhodamine WT were injected in the#2 Shaft at 410 ft below the Steve <br /> Level. On January 29, 2020, alcohol and the tracer Fluorescein were injected in the#2 Shaft at 1,100 ft below <br /> the Steve Level.The alcohol was injected into the mine pool at a lower level of the workings to mix the mine <br /> pool water as the alcohol bubbled up. The tracers were used to evaluate the mixing of the mine pool. These <br /> tracers were water soluble, low toxicity, reasonably stable in normal water environments, and highly <br /> detectable. It is expected that the use of tracers will only be required once.A discussion on the conclusion of <br /> the tracer test is provided in Section E.5.4 and a complete discussion is provided in Appendix 2. <br /> E.S.2.3. In-Situ Treatment Results <br /> During the in-situ treatments,the water quality of the mine pool was frequently monitored at a sample port in <br /> the WTP just before the RO units.The effectiveness of the in-situ treatments is illustrated by a decrease in the <br /> uranium and molybdenum concentrations shown on Figures E-3 and E-4,respectively.As shown on Figure E-3, <br /> dissolved uranium concentrations decreased from approximately 23 mg/L before the first in-situ treatment in <br /> 2013 to a minimum of approximately 2 mg/L, an approximate 90% reduction in concentration. There was a <br /> rebound in dissolved uranium concentrations in 2014,which decreased again after the injections of MicroC® <br /> and molasses in 2015.The dissolved uranium concentrations again rebounded to a maximum of approximately <br /> 40 mg/L before the second in-situ treatment in 2017 followed by a decrease to a minimum of approximately <br /> 4 mg/L,an approximate 90%reduction in concentration.The decreasing uranium concentrations indicate that <br /> JUNE 2021 19 AMENDMENT 6 <br />