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<br />. 00291~ <br /> <br />. <br /> <br />9. Although there are no numerical criteria shown for lithium, this <br />metal was measured at all of the stations, generally occurring <br />at concentrations of less than 25 ~g/l. Excursions above this <br />concentration occurred at Yellow Creek (220 ~g/l), Little Beaver <br />Creek (40 ~g/l), and Milk Creek (60 ~g/l). <br /> <br />. <br /> <br />In order to determine the effect of high suspended solids on metal <br />concentrations, fil tered and unfiltered samples were collected from the <br />White River at Rangely (RM 78.2) on 5/26/76. This sample was extremely <br />muddy (turbidity of 150 FTU and TSS of 600 mg/l) because of high Spring <br />runoff flows. The dissolved and total analyses shown in Table 6 reveal <br />the extent to which the metallic ions adhered to the suspended solids in <br />the water. For example, aluminum, iron, magnesium, manganese, potassium, <br />and zinc were all much more concentrated in the total form than in the <br />dissolved form. The significant difference in the potassium concentrations <br />may be due to a large amount of suspended illite clay which contains <br />appreciable amounts of potassium and is a chief constituent of many <br />shales (Jumikis, 1962; Leonards, 1962). After filtration through a 0.45~ <br />membrane filter, metal concentrations were reduced by as much as 100 times, <br />in the case of aluminum. Concentrations of less common trace metals, such <br />as arsenic, cadmium, chromium, copper, lead, lithium, molybdenum, selenium, <br />and silver were not significantly different in either the dissolved or total <br />form. The calcium concentrations show that the dissolved form was greater <br />than the total form, and the only possible explanation appears to be related <br />to sample contamination. <br /> <br />. <br /> <br />. <br /> <br />. <br /> <br />Non-Meta 1 s <br /> <br />. <br /> <br />Profiles of boron and fluoride concentrations are depicted in Figs. 17 <br />and 18, which show that both of these parameters were usually present at higher <br />concentrations during "low flow" than during "high flow". Concentrations <br />of boron averaged well below the criteria/standard limit of 750 ~g/l ,except <br />for Yellow Creek, which averaged 1025 ~g/l during the "high flow" study. <br />Yellow Creek also contained the highest mean fluoride concentration <br />(2.34 mg/l), which was slightly in excess of the criteria/standard limit <br />of 2.0 mg/l. No other station contained mean fluoride concentrations <br />greater than 0.6 mg/l. <br /> <br />. <br /> <br />Nutrients <br /> <br />. <br /> <br />The nutrient parameters included in this study were total kjehldal <br />nitrogen, nitrite plus nitrate nitrogen, ammonia nitrogen, total phosphorus, <br />and ortho phosphorus. These parameters were analyzed during the "high flow" . <br />study but were not included (they had not been requested) in the earlier <br />"low flow" study. The organic fraction, as measured by TKN, comprised the <br />majority of the nitrogen at each sample location with the highest concentra- <br />tions generally being measured in the lower reach of the White River <br />(see Fig. 19). The highly variable T~N concentrations observed at station <br />NF-18 are thought to be due to analytical difficulties. The profile of <br /> <br />. <br /> <br />39 <br /> <br />. <br /> <br />.J ~:'& <br />