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<br />EFFECT OF URB~N DEVELOPMENT ON STREAM <br />WATER QUA LITY <br /> <br />Regional variations in the quality of <br />surface ~aters arise naturally, deter- <br />~ined by the mineral structure of the <br />geological strata and the chemistry of <br />the surface soils (Berry, et a1. <br />1974). However, it is generally ac- <br />cepted that urban development causes a <br />deterioration in this variable natural <br />quality of ~urface waters. The effect <br />is not a simple one, and methods of <br />predicting it are not well developed. <br />In addition, the manner in which a par- <br />ticular activity or type of development <br />causes a change in water quality may <br />itself he complex (Coughlin and Hammer, <br />1973) . <br /> <br />Among the sources of pollution in urban <br />runoff water are sediments originating <br />from construction sites, debris and <br />contaminants from streets, contaminants <br />from open land areas, ?ublicly used <br />chemicals, air deposited substances, <br />ice control chemicals, and dirt and <br />contaminants washed from vehicles (Sar- <br />tor, et al. 1974). Previous studies <br />provide valuable information on the <br />total problem of water pollution re- <br />sulting from urban runoff. They point <br />out the shock pollution loads which <br />storm runoff from urban areas can place <br />on receiving waters. Principal conclu- <br />sions from many of these studies are <br />listed by Sartor, et al. (1974), Amy, <br />et a1. (1974), McElroy, et a1. <br />(1976), Wanielista, et al. (l977), and <br />by Waugh (1978) as:- <br /> <br />1. Water temperatures can be increased <br />5-8 degrees C in summer and lowered <br />up to 3 degrees C in winter. <br /> <br />2. Concentrations of suspended solids <br />can increase dramatically during <br />urban land development and con- <br />struction. <br /> <br />3. Dissolved load in streams can in- <br />crease up to ten-fold with urbani- <br />sation. <br /> <br />4. With secondary treatment of urban <br />waste water, more than half of the <br />residual pollution in a stream will <br />come from unrecorded and uncon- <br />trolled sources, e.g. urban storm <br />water discharges and runoff frOM <br />farmland. <br /> <br />s. Runoff from street surfaces is gen- <br />erally highly contaminated and is <br />similar in many respects to sanita- <br />ry sewage. Calculations based on a <br />typical city indicate that the ru- <br />noff from the first hour of a mod- <br />erate-ta-heavy storm (brief peaks <br />to at least 1.3 cm/hr) contributes <br />considerably more pollutional load <br />than does the same city's raw sani- <br />tary waste during the same period <br />of time. These calculations are <br />for a situation in which streets <br />ere cleaned (intentionally or by <br />rainfall) about once every five <br />days. <br /> <br />6. The major constituent of street <br />surface contaminants is consistent- <br />ly found to be inorganic, <br />mineral-like matter, similar to <br />common sand and silt. The loading <br />intensities of these contaminants, <br /> <br />expressed as weighted average va- <br />lues for all samples, were found by <br />Sartor, et al. (1974) to be: <br />total solids, 395 kg/curb kmJ <br />volatile solids, 28.2 kg/curb kmJ <br />BODS, 3.80 kg/curb km; COD, 26.8 <br />kg/curb km: phosphates, 0.310 <br />kg/curb kmJ nitrates, 0.026 <br />kg/curb km; Kjeldahl nitrogen, <br />8.620 kg/curb km: total coliforms, <br />61,800 ~illion/curb km: and faecal <br />coli forms, 3,480 million/curb km. <br /> <br />. <br /> <br />The extreme variability of water <br />quality in urban storm water is de- <br />monstrated by wanielista, ct al. <br />{1977}. Ranges of para~eter va- <br />lues, exoressed as conc~ntr~tions, <br />are stated to be: tot~l solids, <br />451 to 14,6~a mg/l: total suspen~- <br />ed solids, 2 to 11,303 mg/l: <br />volatile suspended solids, 12 to <br />1,60W mg/l; BODS, 1 to 70B mg/l; <br />COD, 5 to 3,10~ mg/l: total P04, <br />0.1 to 125 mg/l: soluble P04, 0.1 <br />to Ig mg/l; organic N, 0.1 to 16 <br />mg/l: NH3-N, 0.1 to 2.5 mg/l: <br />chlorides, 2 to 25,000 mg/l (with <br />highway deicing): total coliforrns, <br />280 to 146 mi1lion/100ml; faecal <br />coliforms, 55 to 112 million/100ml~ <br />and faecal streptococci, 200 to 1.2 <br />million/100m!. <br /> <br />! <br /> <br />7. Significant amounts of heavy metals <br />were detected in the contaminant <br />materials. zinc and lead were the <br />most prevalent, and for the cities <br />tested yielded average values of <br />8.183 and a.e56 kg/curb km respec- <br />tively. <br /> <br />8. Substantial quantities of organic <br />pesticides and related compounds <br />were also found in the street sur- <br />face contaminants~ Although the <br />data showed considerable variation <br />from. site to site, loads in the <br />order of 0.00028 kg/curb km were <br />found for the cities tested. Both <br />chlorinated hydrocarbons and poly- <br />chlorinated biphenyl compounds <br />(PCB) were found rather consistent- <br />ly. <br /> <br />. <br /> <br />. <br /> <br />9. Grease and oil are the major organ- <br />ic constituents of street particu- <br />lates, and are shown to occur with <br />concentrations up to 110 mg/l. <br /> <br />11. The quantity of contaminant materi- <br />al on street surfaces varies wide- <br />ly. Principal factors which affect <br />the loading intensity at any given <br />site include surroundina land use, <br />elapsed time since streets were <br />last cleaned, local traffic volume <br />and character, street surface type <br />and condition, public works prac- <br />tices, and season of the year. In <br />general, industrial land use areas <br />tend to accumulate contaminants <br />faster than commercial or residen- <br />tial areas~ <br /> <br />. <br /> <br />11. Loading intensities were found by <br />Sartor, et al. (1974) to average <br />791 k9/curb km for industrial <br />aites, Bl.R kg/curb km for commer- <br />cial areas, and 338 kg/curb km for <br />residential areas. <br /> <br />. <br /> <br />12. Total colifocms are higher in in- <br />dustrial than commercial areas, and <br />lowest in residential areas. <br />