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<br />Water Quality Control at Rocky Flats: <br />A Wet Detention Model for Stormwater RadionucHde Removal <br /> <br />Ian Paton, Rocky Mountain Remediation Services, L.L.C. (RMRS) <br />George S. Squibb, RMRS and Water Measurement Technologies, Inc. <br />Gregory A. Wetherbee, RMRS and Water Measurement Technologies, Inc. <br /> <br />Abstract <br /> <br />The removal of radionuclides from stormwater using a wet detention pond was modeled for South Walnut <br />Creek and Pond B-5 at the Rocky Flats Environmental Technology Site (Site), a Department of Energy <br />facility formerly used for the production of nuclear weapons components. Site wet detention ponds are used <br />to remove plutonium activity, predominantly bound to particulates, from stormwater. A model was <br />developed to relate particle size and particle settling velocity within the pond using a variation of Stokes' <br />Law. The model was used to estimate the minimum particle size that would be removed by settling, given <br />estimated overflow rates based on the flow of stormwater through the pond. Using the plutonium activity in <br />the storm water influent to the pond, the maximum allowable inflow rate that can occur without discharging <br />plutonium in excess of stream standards was estimated. This settling model can be applied to other <br />contaminant removal applications in wet detention facilities. Verification of the modeled results will <br />facilitate more cost effective stormwater management at the Site. <br /> <br />Introduction and Obiectives <br /> <br />The Rocky Flats Environmental Technology Site (Site) is a United States Department of Energy (DOE) <br />facility, formerly used in the production of nuclear weapons components and now undergOing <br />decommissioning and remediation. All surface water flowing over the Site's core industrial area is <br />managed in a system of wet detention ponds before being released offsite. One of these pond systems was <br />modeled to determine its effectiveness in removing plutonium, the contaminant of greatest concern, from <br />Site stormwater runoff. <br /> <br />The purpose of the modeling effort described herein is to assess the effect of an individual detention pond in <br />removing plutonium through settling. taking into consideration known hydrologic characteristics of the <br />drainage, including plutonium activity in the stormwater runoff. The ultimate goal of the project was to <br />assess the maximum allowable flow rate through the pond while remaining in compliance with a given <br />plutonium activity discharge standard. <br /> <br />Backeround <br /> <br />The Site is under close scrutiny by local communities because it is the Nation's largest repository of special <br />nuclear material (SNM), namely plutonium-239,240. Past accidents, management practices, and waste <br />disposal at the Site created contaminated areas which present potential risks to environmental quality. <br />Stormwater runoff from the Site Industrial Area (IA) transports radionuclides from contaminated areas to <br />detention ponds; which are monitored for compliance with State stream standards. <br /> <br />The stream standard for plutonium-239,240 is 0.05 picocuries I Liter which is very close to analytical <br />detection limits (Minimum Detectable Activity = 0.01 picocuries I Liter). Pu-239,240 activity in <br />stormwater runoff in North Walnut Creek and South Walnut Creek has been measured between 0.07 pCiIL <br />and 5.0 pCiIL. Pu-239,240 activities in the detention ponds have been below the 0.05 pCiIL limit for the <br />past five years, except for one large storm on May 17, 1996 which passed through the detention ponds <br />without adequate time for settling of the particulate-bound Pu-239.240. <br />