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affect human health and aquatic ecosystems. In the <br />UCOL, water samples were collected at four sites <br />(fig. 1) during 1996-98 to determine temporal and <br />spatial variations in the occurrence and concentrations <br />of pesticides. A synoptic study of 43 sites (fig. 2) was <br />completed in 1998 to determine the spatial distribution <br />of pesticide concentrations within agricultural areas of <br />the UCOL. <br />Purpose and Scope <br />The purposes of this report are to (1) describe <br />pesticide concentrations in rivers, streams, and drains <br />in the UCOL study unit during 1996-98 and (2) deter- <br />mine the distribution of pesticide detections and <br />concentrations among different land uses, site types, <br />and agricultural subbasins in the study unit. Surface- <br />water sites in the UCOL basin were sampled, and <br />samples were analyzed for a series of pesticide <br />compounds to temporally and spatially describe pesti- <br />cide concentrations. Four river and stream sites in the <br />study unit were sampled frequently for up to one year. <br />Forty-three river, stream, and drain sites in agricultural <br />areas of the study unit were sampled once during a <br />synoptic study. <br />Description of the Upper Colorado River <br />Basin study unit <br />The UCOL study unit has a drainage area of <br />about 17,800 mid (fig. 1), all located in western Colo- <br />rado except for about 100 mi'` in eastern Utah (Driver, <br />1994). The study unit is divided almost equally into <br />two physiographic provinces-the Southern Rocky <br />Mountains in the east and the Colorado Plateau in the <br />west (fig. 1). The environmental setting of the UCOL <br />study unit and its physiographic provinces has been <br />described by Apodaca and others (1996). <br />Land uses in the UCOL study unit include <br />rangeland or forest, mining, urban, and agriculture. <br />Rangeland or forests make up about 85 percent of the <br />study unit area and are used for recreation, wildlife <br />habitat, livestock grazing, and logging. Tourism and <br />recreation are the major land-use activities in the <br />Southern Rocky Mountains province, and agriculture <br />is the predominant land-use activity in Delta, Mesa, <br />and Montrose Counties in the Colorado Plateau. <br />Tourism, recreation, and agriculture are all important <br />land-use activities in Gunnison County, located mostly <br />in the Southern Rocky Mountains physiographic prov- <br />ince. Because of the semiarid climate (generally, less <br />than 10 in/yr of precipitation in the western valleys), <br />little agricultural production is possible without irriga- <br />tion. Irrigation takes place mainly in river valleys and <br />in low-altitude areas of the Colorado Plateau. In the <br />Grand and Uncompahgre River Valleys (fig. 2), agri- <br />cultural areas are supported by an extensive system of <br />canals and ditches. About 97 percent of the off-stream <br />water use in the study unit is for irrigation (Apodaca <br />and others, 1996). <br />The major crops produced in the study unit are <br />alfalfa and other hay, corn (grain and silage), dry <br />beans, grains, vegetables (primarily sweet corn and <br />onions), fruit (apples, tart cherries, peaches, and <br />pears), melons (cantaloupe and watermelon), and <br />grapes for wine production. Acreage and production <br />data for Colorado in 1997 are available by county for <br />alfalfa, other hay, corn (grain and silage), dry beans, <br />winter and spring wheat, barley, and oats (Colorado <br />Department of Agriculture, 1998) and are shown in <br />table l for 10 counties in the study unit. Alfalfa and <br />other hay together were the major crops produced in <br />each county in 1997 and were the only crops tallied for <br />Eagle, Grand, Gunnison, Ouray, Pitkin, and Summit <br />Counties. Dry beans and corn also were commonly <br />harvested in Delta and Montrose Counties, while corn <br />and winter wheat were commonly produced in Mesa <br />County in 1997. Most (97.6 percent) of the harvested <br />acreage was irrigated. Alfalfa, other hay, and winter <br />wheat were produced on the nonirrigated land. <br />Acreage and production data for individual counties <br />were not available for vegetables, fruit, melons, and <br />grapes. <br />Pesticide-use data for the 1996-98 sampling <br />period were not available for the study unit. Pesticide <br />use by crop type in Colorado was estimated by <br />Bohmont (1991, 1993) for seven regions in the State <br />for l 989 and statewide for 1992. In the ] 989 survey, <br />four counties (Garfield, Mesa, Delta, and Montrose) of <br />the UCOL study unit were represented as the West <br />Central agricultural region. Ouray County was <br />included in the Four Corners region, and no pesticide- <br />use data were reported for Eagle, Grand, Gunnison, <br />Pitkin, and Summit Counties. The six most common <br />pesticides applied to irrigated crops in the West <br />Central agricultural region in 1989 were (1) EPTC, <br />(2) alachlor, (3) 2,4-D, (4) parathion-ethyl [parathion], <br />(5) metolachlor, and (6) atrazine, as measured by <br />INTRODUCTION <br />