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Pesticides in Surface Waters of the Upper <br />Colorado River Basin, Colorado, 1996-98 <br />By Nancy J. Bauch and Norman E. Spahr <br />Abstract <br />Forty-four river, stream, and drain sites in <br />the Upper Colorado River Basin in Colorado were <br />sampled during 1996-98 to determine the occur- <br />rence and distribution of pesticides in the basin. In <br />afixed-station study, 57 surface-water samples <br />were collected from October 1996 through <br />January 1998 at four sites. Each site was sampled <br />approximately monthly for up to a year, with <br />more frequent sampling during the spring and <br />summer growing season. In a synoptic study, <br />surface-water samples were collected at 43 sites <br />in the agricultural areas of the Grand Valley and <br />the Uncompahgre River Valley in May 1998. <br />Each site was sampled once. <br />Pesticide concentrations generally were low <br />and varied seasonally and across land uses. <br />Thirty-five pesticides were detected at least once <br />in the two studies, and 11 pesticides accounted for <br />almost 82 percent of the detections. Herbicides <br />were more commonly detected than insecticides, <br />and only the herbicides alachlor and atrazine were <br />detected in more than 50 percent of the samples. <br />Carbofuran was the most commonly detected <br />insecticide and was detected in 19 percent of the <br />samples. Pesticide detections increased and were <br />measured at higher concentrations in the summer <br />months and at the agriculture sites. All pesticide <br />concentrations were less than drinking-water <br />standards, and most complied with human-health <br />advisories and criteria for the protection of fresh- <br />water aquatic life. Pesticides in the Upper Colo- <br />rado River Basin in Colorado were detected <br />slightly less frequently and generally at lower <br />concentrations than in 20 National Water-Quality <br />Assessment Program study-unit basins that <br />collected water-quality data from 1992 through <br />1996. Results from surface-water sampling <br />conducted during 1996-98 in the Upper Colorado <br />River Basin in Colorado indicate that beneficial <br />uses of water were not being impaired by the <br />presence of pesticides in surface waters in the <br />basin. <br />INTRODUCTION <br />In 1991, the U.S. Geological Survey (USGS) <br />began full implementation of the National Water- <br />Quality Assessment (NAWQA) Program. The goals <br />of the NAWQA Program are to (1) describe current <br />water-quality conditions for a large part of the <br />Nation's freshwater streams, rivers, and aquifers; <br />(2) describe how water quality is changing over time; <br />and (3) improve understanding of the primary natural <br />and human factors that affect water-quality conditions <br />(Leahy and others, 1990). Many of the Nation's most <br />important river basins and aquifers, represented as <br />study units, are being investigated through the <br />NAWQA Program. The Upper Colorado River Basin <br />(UCOL) study unit (fig. 1), located primarily in <br />western Colorado, is one of the NAWQA study units. <br />As part of the NAWQA Program, investigations of the <br />hydrology and water quality of the UCOL began in <br />1994. The occurrence and distribution of pesticides in <br />surface water are two of the main topics of interest in <br />the NAWQA Program. Issues of concern include the <br />types and concentrations of pesticides in the Nation's <br />rivers and streams, seasonal distribution of pesticides, <br />relation of pesticide occurrences and concentrations to <br />land use, and potential of pesticide concentrations to <br />Abstract <br />