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<br />, <br /> <br />l\:l <br />""'" <br />CD <br />CO <br /> <br />O'r/) <br />gcn <br />O'~ <br />.-;E=l <br />~...... <br />~z <br />0::: <br />""1 ,0 <br />p::; ....... <br />o it-< <br />....l ..<C <br />::c: '0::; <br />~S <br />00 <br />............ <br /> <br />~[ <br /> <br />Salinity Increases in the Navajo Aquifer in Southeastern Utah <br /> <br /> <br />., <br /> <br />" <br /> <br />" <br /> <br />." <br /> <br />'" <br /> <br />10- <br /> <br />I::. <br /> <br />TREND LINE THROUGH <br />NAVAJO AQUIFER <br />DATA <br /> <br />I::. <br /> <br />1 <br /> <br />.1::./ <br /> <br />".A ^ <br />'. L.> I::. <br />. I::..~ <br />.~ I::. <br /> <br />1::.1::. ~~NAI::.I::. <br /> <br />I::. b."'~ <br />IODIDE- TO-CHLORIDE RATIO . <br />TYPICAL OF HALITE-SOLUTION <br />BRINES (RlCH1ER AND KREITLER, I::. <br />1991) ~ I::.A <br /> <br /> <br />~ <br /> <br />. <br /> <br />,-I <br />!i <br />., <br /> <br />; <br />'l <br />, <br /> <br />0.1 <br /> <br />.., <br /> <br />. <br /> <br />... <br /> <br />"I <br /> <br />1 10 100 1,000 10,000 100,000 <br />CHLORIDE CONCENlRATION, IN <br />MILLIGRAMS PER KILOGRAM <br /> <br />EXPLANA TION <br /> <br />A NAVAJO AQUIFER <br />. OIL-FIELD BRINE--Number <br />above symbol refers to <br />multiple samples. <br /> <br />Figure t Iodide-ta-Chloride Weight, Ratios Compared with Chloride Concentration in Water Samples <br />from the ,Navajo Aquifer and Oil~Field Brines in the Study Area. <br /> <br />Iodide-to-chloride weidht ratios in samples from the <br />Navajo aquifer trend ~ward lower ratios characteris- <br />tic of non-OFB (halite solution brine) ratios (Fig; <br />ure 7), The best fit liqe through the Navajo aquifer <br />samples trends toward'the composition of halite solu- <br />tion brines and is far rElmoved from the composition of <br />OFB in the study area! (Figure 7), Results of the bro- <br />mide and iodide data are in agreement and indicate <br />that OFB is not causing the salinity increases in the <br />Navajo aquifer. . <br /> <br />Stable Isotopes <br /> <br />discounting the role of OFB as even a minor. source of <br />salinity to water in the Navajo aquifer, additional geo- <br />chemical evidence is needed to verify these initial <br />results. The stable isotopes of oxygen and hydrogen in <br />water provide a useful geochemical tool to 4etermine <br />water sources (Drever, 1988) and hence salinity. <br />sources, The stable isotopes of oxygen (180 and 160) <br />and hydrogen (2H and lH) have been used in numer- <br />ous OFB studies to differentiate salinity sources <br />(Richter and Kreitler, 1991), The application of 11180 <br />and IlD values to differentiate salinity sources is par- <br />ticularly well suited to this study area because of the <br />large differences in isotopic composition between OFB <br />and other ground and surface waters (Figure 8), <br />The isotopic composition of ground- and. surface- <br />water samples in the study area was compared with <br /> <br />" .<0. <br />;w <br />~:~ <br />,:r <br />i~ <br />~# <br />~, <br />"S <br />:1 <br />", f~ <br /> <br />Although the bromide-to-chloride and iodide-to- <br />chloride weight ratios' provide strong evidence for <br /> <br />, ,i", ,J <br /> <br />1129 <br /> <br />~ <br />:1 <br />~ : <br />'~j <br />~i <br /> <br />WATER RESOURCES BULLETIN <br /> <br />'v "_-,, _>"."c;;'~" <br /> <br />, ik.~'\, ~.~}*"i *,0 ,-~j' <br />