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STATE OF COLORADO <br />DIVISION OF MINERALS AND GEOLOGY <br />Department of Natural Resources <br />1313 Sherman St., Room 215 <br />Denver, Colorado 80203 <br />Phone: (303) 866-3567 <br />FAX: (303) 832-8106 <br />Memorandum <br />DIVISION OF <br />MINERALS <br />GEOLOGY <br />RECLAMATION <br />MINING•SAFETY <br />Date: JUIy 11, 2002 Rill Owens <br />Governor <br />I Greg E Watcher <br />From: Tom Kaldenbach Executive Director <br />Ronald W. Cattany <br />To• Janet Binns Acting Division Director <br />Re: Musgrave well near the Trapper Mine, Permit C-81-010 <br />Introduction - I have attempted to identify the cause of the change in water quality in the <br />Musgrave well. The change has been described as a brownish red stain, sulfur odor, and <br />bad taste. My approach to identifying the cause of the change was to: 1) determine if the <br />Musgrave well is in the predicted subsurface flow path of coal spoil leachate, if any has <br />been generated by nearby mining, and 2) attempt a chemical match of the Musgrave well <br />water and coal spoil leachate. <br />Musgrave well location relative to mining -The well's completion report on file with the <br />Office of the State Engineer indicates it produces water from the uppermost 10 feet of the <br />3`a White Sandstone. DMG sampled the well on 5/7/02. The nearest coal mine <br />monitoring well is Trapper's well 81-03a located about one-half mile northeast of the <br />Musgrave well. The Musgrave well could be within the predicted flow path of any <br />leachate flowing from the Trapper Mine's Browning Pit, based on the map of the 3`a <br />White's potentiometric surface in Trapper's 2001 annual report. The Browning pit was <br />backfilled in the late 1980s. It is not known if the Browning pit has generated leachate <br />because there is no spoil monitoring well in the pit. Also, Trapper's only 3`a White <br />Sandstone monitoring well (well GE-3) that is between the Musgrave well and the <br />Browning pit does not provide reliable data because its perforated interval straddles the <br />2"a White Sandstone and the 3`a White Sandstone. The Musgrave well probably is not <br />within the flow path of any of the mining that occurred at the Empire Mine. <br />Musgrave well sample results -The cation/anion balance in the analysis had a 7% <br />difference, an acceptable amount. The sample was asulfate-calcium-magnesium- <br />bicarbonate type water. The dominant anion was sulfate. Total dissolved solids <br />concentration was 1900 mg/1; sulfate was 870 mg/1. Metals included iron (1.85 mg/1), <br />magnesium (155 mg/1), and manganese (0.178 mg/1). The manganese or iron <br />concentration could cause the reported stain. The manganese concentration could cause <br />the bad taste. <br />Comparison of Musgrave well sample results with Trapper's coal spoil leachate - <br />Trapper monitors leachate quality in four wells on the mine. Although none of the wells <br />