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ADZ Laboratories, Inc. <br />2773 Downhill Drive Steamboat Springs, CO 80487 <br />Golder Associates <br />ACZ Project ID: L11197 <br />ID WORKNUM PARAMETER <br />METHOD <br />QUAL <br />DESCRIPTION <br />'ACZ <br />L11197 -08 WG340820 Barium, dissolved <br />M200 7 ICP <br />M3 <br />The spike recovery value is unusable since the analyte <br />level The recovery of the associated control sample (LCS <br />concentration in the sample is disproportionate to the spike <br />level The recovery of the associated control sample (LCS <br />WG341153 <br />Chloride <br />M300 0 - Ion Chromatography <br />or LFB) was acceptable <br />Sodium, dissolved <br />M200 7 ICP <br />M3 <br />The spike recovery value is unusable since the analyte <br />calibration range <br />WG341222 <br />concentration in the sample is disproportionate to the spike <br />SM450OF -C <br />RA <br />Relative Percent Difference (RPD) was not used for data <br />level The recovery of the associated control sample (LCS <br />or LFB) was acceptable <br />WG341222 Fluoride <br />SM450OF -C <br />RA <br />Relative Percent Difference (RPD) was not used for data <br />accurate evaluation (< 10x MDL) <br />WG340929 <br />pH <br />validation because the sample concentration is too low for <br />ZW <br />Method deviation The sample was centrifuged prior to <br />accurate evaluation (< 10x MDL) <br />WG341153 Sulfate <br />M300 0 - Ion Chromatography <br />RA <br />Relative Percent Difference (RPD) was not used for data <br />Residue, Filterable (TDS) @180C <br />SM2540C <br />ZO <br />validation because the sample concentration is too low for <br />accurate evaluation (< 10x MDL) <br />WG340929 Total Alkalinity <br />SM23208 - Titration <br />RA <br />Relative Percent Difference (RPD) was not used for data <br />RA <br />Relative Percent Difference (RPD) was not used for data <br />validation because the sample concentration is too low for <br />validation because the sample concentration is too low for <br />accurate evaluation (< 10x MDL) <br />L11197 -09 WG340820 <br />Barium, dissolved <br />M200 7 ICP <br />M3 <br />The spike recovery value is unusable since the analyte <br />concentration in the sample is disproportionate to the spike <br />level The recovery of the associated control sample (LCS <br />or LFB) was acceptable <br />WG341153 <br />Chloride <br />M300 0 - Ion Chromatography <br />DC <br />Sample required dilution Non - target analyte exceeded <br />calibration range <br />WG341222 <br />Fluoride <br />SM450OF -C <br />RA <br />Relative Percent Difference (RPD) was not used for data <br />validation because the sample concentration is too low for <br />accurate evaluation (< 10x MDL) <br />WG340929 <br />pH <br />SM4500H+ B <br />ZW <br />Method deviation The sample was centrifuged prior to <br />analysis due to high solid content <br />WG340923 <br />Residue, Filterable (TDS) @180C <br />SM2540C <br />ZO <br />Concentration is based on a final residue greater than 200 <br />mg <br />WG341153 <br />Sulfate <br />M300 0 - Ion Chromatography <br />RA <br />Relative Percent Difference (RPD) was not used for data <br />validation because the sample concentration is too low for <br />accurate evaluation (< 10x MDL) <br />WG340929 <br />Total Alkalinity <br />SM2320B - Titration <br />ZW <br />Method deviation The sample was centrifuged prior to <br />analysis due to high solid content <br />REPAD.15.06 05.01 <br />Page 23 of 26 <br />