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SECTION 5 <br />SAMPLING PROCEDURES AND ANALYSIS <br />The following sampling procedures will be followed to ensure that water levels and quality can be <br />reliably compared from well to well and from sampling event to sampling event and that the data are <br />reproducible. This section also outlines the laboratory analyses required for each groundwater <br />sample. <br />5.1 Sampling Protocols <br />Prior to beginning sampling, field instruments will be calibrated following the manufacturers' <br />instructions. Calibration information and results will be documented in the field notebook each <br />time a field instrument is calibrated for use in this sampling effort. <br />5.1.1 Monitoring Wells MW -001A, MW -002, MW -003, and MW -004. Following is the <br />protocol that will be followed for groundwater sampling at MW -001A, MW -002, MW -003, and <br />MW -004. Note that MW -001A will be checked for water during each sampling event, and <br />groundwater samples of this well will be taken only if there is water in the well. <br />• Measure the depth to groundwater from the top of the casing using an electric well <br />probe and engineer's scale. <br />• Purge a minimum of three casing volumes. It is possible monitoring wells installed in <br />the St. Charles alluvial aquifer will be purged dry prior to removing three well casing <br />volumes. During dry seasons, well recharge rates may be slow and prevent sample <br />collection following purging the well dry. To assure a sample is collected from each <br />well during the sampling event, purge water from the first well volume removed will be <br />collected in laboratory- prepared containers and stored until the purge is complete. If <br />the well is purged dry and measurable recharge is not observed, the sample collected <br />from the first well volume will be submitted for analysis. If groundwater is not <br />detected at all, the total depth of the monitoring well will be measured to confirm <br />that the screened interval has not become filled with sediment or collapsed. When <br />water is not available for analysis, observations of the well condition will be reported. <br />• Purge the wells using a bailer or a peristaltic pump. The well purge water will be <br />discharged and allowed to infiltrate into the soil or flow in a nearby arroyo. <br />■ Record field water quality measurements in the field notebook at the start of purge <br />and after removing the first, second, and third casing volumes. Field water quality <br />measurements include pH, specific conductance /electrical conductivity (SC /EC), and <br />temperature. <br />■ Collect the groundwater sample using a bailer or peristaltic pump and fill laboratory- <br />prepared containers assigned to the well. <br />• Submit the groundwater samples to an EPA - certified laboratory for analysis. <br />P:\ Dan \GEN \FS -P -T \22421 \Permitting \Stipulation Response \ Groundwater Sampling Plan \Conduson 1 Groundwater Sampling Plan 3_24_03.doc <br />7 <br />