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ACZ Laboratories, Inc. <br />2773 Downhill Drive Steamboat Springs, CO 80487(800) 334 -5493 <br />Rio Grande Silver, Inc. <br />Project ID: S12064 <br />Sample ID: WRSF -C <br />Wet Chemistry <br />Parameter <br />EPA Method <br />Result Quai XQ Units MDL PQL <br />Date Analyst <br />Alkalinity (1312 DI) <br />Bicarbonate as <br />CaCO3 <br />Carbonate as CaCO3 <br />Hydroxide as CaCO3 <br />Total Alkalinity <br />Chloride (1312 DI) <br />Fluoride (1312 DI) <br />Nitrate (1312 DI) <br />Nitrate /Nitrite as N <br />(1312 -DI) <br />Nitrite as N (1312 -DI) <br />Nitrogen, ammonia <br />(1312 -DI) <br />Phosphorus, ortho <br />dissolved (1312 -DI) <br />Sulfate (1312 DI) <br />SM2320B - Titration <br />M365 1 - Automated Ascorbic <br />Acid <br />0516 -02 - Turbidimetnc <br />17 <br />3 <br />0.07 <br />B <br />B <br />U <br />20 <br />SM4500CI -E U <br />SM4500F -C U <br />Calculation: NO3NO2 minus NO2 0 08 BH <br />M353 2 - Automated Cadmium 0 09 BH <br />Reduction <br />M353 2 - Automated Cadmium 0 01 BH <br />Reduction <br />M350 1 - Automated Phenate 0 07 B <br />H <br />U <br />* mg /L <br />* mg /L <br />* mg /L <br />* mg /L <br />* mg /L <br />mg /L <br />* mg /L <br />ACZ Sample ID: <br />Date Sampled: <br />Date Received: <br />Sample Matrix: <br />Inorganic Analytical <br />Results <br />2 <br />2 <br />2 <br />1 <br />0.1 <br />0 02 <br />0.02 <br />20 <br />20 <br />20 <br />5 <br />0.5 <br />0.1 <br />01 <br />L97087 -03 <br />09/28/12 13:56 <br />10/02/12 <br />Soil <br />mg /L 2 20 10/15/12 0:00 abm <br />10/15/12 0 00 <br />10/15/12 0 00 <br />10/15/12 0 00 <br />10/16/12 9 48 <br />10/15/12 12 01 <br />10/22/12 11 40 <br />10/12/12 23 <br />abm <br />abm <br />abm <br />Ihb <br />abm <br />calc <br />pjb <br />mg /L 0.01 0.05 10/18/12 23 51 pjb <br />mg /L 0.05 0 5 10/18/12 13 24 tcd <br />mg /L 0 01 0 05 10/12/12 22:26 pjb <br />mg /L 1 5 10/17/12 15:53 Ihb <br />REPIN 02 06 05 01 * Please refer to Qualifier Reports for details <br />Page 11 of 57 <br />