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Repoit to <br />Name: Randy McClure <br />Company: Rio Grande Silver, Inc. <br />E -mail: rmcclure@hecla- mining.com <br />Copy of Report to. <br />Name: Cassady Harraden <br />Company: Rio Grande Silver, Inc. <br />Invoice to <br />Name: Wendy Leggin <br />Company: Rio Grande Sliver, Inc. <br />E-mail: wleggitt`hecla- mining.com <br />ACZ Laboratories, Inc. <br />2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334 -5493 <br />Quote #: <br />Project/PO #: <br />Shipping Co.: <br />Tracking #: <br />Reporting state for compliance testing: <br />Are any samples NRC licensable material? <br />SPLPABA -E39 <br />SPLPABA <br />SPLPABA -E100 <br />FRMQA021.12.03.06 <br />t <br />SPLPABA -10250 1 8/20(2012 14:00 <br />8/20/2012 14:00 <br />8120/2012 14:00 <br />8/20/2012 14:00 <br />(W9g <br />r 13,rs .57., <br />CHAIN 01 <br />CUSTODY <br />Address: <br />Telephone: ( 658 -1080 <br />E-mail: <br />P.O. Box 610 <br />Creede, Colorado 81130 <br />charraden(r@hecla- mining.com <br />Telephone: (775) 217 -5093 <br />Address: <br />P.O. Box 610 <br />Creede, Colorado 81130 <br />T (719) 658 -1080 <br />If samples) received past holding time (HT), or if Insufficient HT remains to complete <br />analysis before expiration, shall ACZ proceed with requested short HT analyses? <br />If "NO" then ACZ will contact client for further Instruction. If neither "YES' nor "NO" <br />Is Indicated. ACZ will proceed with the requested analyses, even H HT is expired, and data will be qualified. <br />e• <br />YES <br />NO <br />ROCK 1 <br />1 <br />c <br />0 <br />0 <br />9k <br />ROCK <br />ROCK <br />ROCK <br />AIL <br />Matrix SW (Surface Water) • GW (Ground Water) • WW (Waste Water) • DW (Drinking Wale ) • SL (Sludge) • SO (Soil) • 01. (Oil) 011ie (Specify) <br />Please re-run SPLP ONLY for these four (4) samples for the following elements: Al, Sb, As, Ba, Be, B. <br />Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Hg, Mo, Ni, K, Se, Si, Silicon, Ag, Na, Th, U, and Zn. Thanks! <br />J 9` /!s /,Z <br />White - Return with sample. <br />Of <br />• <br />RELINQLPSHED BY. DATE <br />RECEIVED BY: DATE TIME <br />0 AlliP2r11 I <br />/f7 <br />Pace <br />Yellow - Retain for your record <br />Page 39 of 39 <br />