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Overburden Zone Ground Water Ouality Water level monitoring and the piezometric maps <br />show the nearly immediate response of most of the nine new monitoring holes to the seasonal <br />surface irrigation, with water levels going up and down corresponding to the periods when water <br />is in the 2 Park Lateral Ditch. The impression is that the Overburden Zone is annually being <br />flushed with relatively good quality irrigation water. This further suggests that water quality <br />would improve during periods of irrigation and deteriorate during periods when the ditch is dry. <br />However, comparison of the ground water quality data, (see data in Appendix 2.04.7 -1) with the <br />water level data reveals no such correlation. Table 2.04.7 -1 is a summary of the water quality <br />analyses for the Overburden Zone, showing the minimum, maximum, and average values of the <br />analyzed parameters. No data for overburden monitoring hole GW -N55 is shown as this hole <br />was nearly dry to the point that there was not enough water to collect water samples. The <br />summary of the analyses for holes GW -N49 and GW -N52 are also compared with the WQCC <br />(Regulation 41, The Basic Standards For Ground Water) drinking water and agricultural quality <br />standards. The results show the overburden water quality to be unsuitable for domestic drinking <br />water primarily for sulfates. With the exception of calcium and bicarbonate, the water quality at <br />GW -N52 is better than that at GW -N49, most probably the result of being located closer to the <br />seasonal more alkaline recharge from the 2 Park Lateral irrigation ditch. The values for pH at <br />GW -N52 are also somewhat higher (more alkaline). Again, suggesting that being closer to the <br />main source of recharge (the ditch) affects the water quality to a greater extent at GW -N52 than <br />at GW -N49. <br />Coal Zone Ground Water Quality Quarterly groundwater quality samples were collected from <br />the three holes (GW -N48, GW -N51 and GW -N54) beginning on October 10, 2008. The <br />groundwater quality data is contained in Appendix 2.04.7 -1 along with the water level and graph <br />information. Review of the coal zone quality does not clearly reveal any correlation with the <br />irrigation seasons, although there is a slight increase in Ca, CaCO SO and total dissolved <br />solids (TDS) during the winter months when the ditch is not running It may require a few more <br />seasonal irrigation cycles to validate this initial impression. Again, the monitoring hole located <br />furthest up -dip and closest to the recharge area, GW -N51, has better water quality. As an <br />example, the average TDS at GW -N51 is 950 mg/1 compared with an average at GW -N48 of <br />1592 mg/1 and an average TDS at GW -N54 of 5058 mg/1, which is located the furthest down -dip <br />and away from the recharge area. Table 2.04.7 -2 is a summary of the Coal Zone ground water <br />quality showing the min/max and average parameter values since monitoring began. Water <br />quality for the Coal Zone at GW -N54 is the poorest of quality of all nine of the new monitor <br />holes. The values when compared with the WQCC water quality standards clearly show that <br />water from the Coal Zone is unsuitable for domestic drinking water. <br />Ground water monitoring hole GW -N9 (see Map 2.04.7 -1) was installed by Peabody and <br />quarterly water analyses were conducted on samples from this hole from October 1979 to <br />October 1987. This monitoring hole is located within the NHN permit area and is open to both <br />the Overburden and Coal zones. The quality data for this hole is reported in the New Horizon 1 <br />Mine Area permit, pages 7 -4 -49 to 7 -4 -53. The average TDS for the period was 3785 mg/1 and <br />the average SO4 concentration was 2423 mg/l. The values of these two parameters are <br />significantly higher than the Coal Zone values at GW -N48 and GW -N51. This indicates that <br />water quality in the Coal Zone (and probably the OB Zone as well) is also dependent on depth or <br />isolation beneath the weathered zone as well as distance from the recharge area. Therefore, <br />Section 2.04.7 Page 8 November 2011 <br />