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<br />52 <br />~' used to characterize the stream inpu~ from the dump. • <br />The estimated changes in selected water quality parameters as the result <br />of deep percolation in a wet year are shown in Table 14. Even this worst- <br />case estimate indicates a very small effect on the water quality in the <br />stream. The sodium adsorption ratio (SAR) downstream of the waste pile was <br />1 computed by using the computed downstream concentrations of sodium, calcium, <br />and magnesium. <br />' The active waste dump rests on alluvial material directly adjacent to <br />the stream. The alluvium provides a degree of storage, in addition to that <br />~ in the dump itself, and tends to cause seepage into the stream to occur at <br />a reduced rate, but over a longer period of time. Thus, the discharge of <br />0.01 cfs from the waste material, based on a 30 day seepage period, may be <br />larger than actually occurs. The small seep observed during this investi- <br />gation issued from the refuse pile near the contact between the waste and <br />the native ground, and was several feet higher than the water table in the <br />f alluvium. Apparently, the seepage occurred from a water table perched with- . . <br />l in the dump. Evidence of other perched water in the pile was not observed <br />and it is believed that the bulk of deep percolation enters the alluvium <br />before discharge to the stream. Figure 14 compares the composition plots <br />of alluvial waters with that in the adjacent stream. The alluvium shows <br />concentrations of sodium and sulfate that are elevated in respect to the <br />stream beyond that attributable to the overall elevated salt concentration. <br />In the case of sodium, a similar elevation was observed in the alluvium at <br />the Maxraell Mine where it was not possible fora refuse pile to have caused <br />the change in composition. However, the shift in composition toward in- <br />creased sulfate was not observed elsewhere. Table 13 shows a substantial <br />concentration of sulfate in seepage from the waste pile and, in all probability, <br />the seepage is responsible for the shift in composition. <br />The elevated levels of sulfate in the waste dump are somewhat: surprising <br />in view of the fact that all other data on subsurface waters indicate sodium- <br />bicarbonate waters. There is evidence to suggest that the observed sulfate <br />does not derive from sulfuric acid production from pyrite. Four samples . <br />of the waste dump materials were analyzed for pyritic sulfur, showing only <br />low quantities ranging from 0.03-0.04 percent. Also, the pH of 8.0, Tow <br />