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ACZ Laboratories, Inc. <br />2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334 -5493 <br />Kerr Coal Company <br />Project ID: <br />Sample ID: <br />Field Data <br />e <br />Conductivity (Field) <br />pH (Field) <br />Temperature (Field) <br />Metals Analysis <br />Calcium, dissolved <br />Iron, dissolved <br />Magnesium, dissolved <br />Manganese, dissolved <br />Potassium, dissolved <br />Sodium, dissolved <br />Wet Chemistry <br />Alkalinity as CaCO3 <br />Bicarbonate as <br />CaCO3 <br />Carbonate as CaCO3 <br />Hydroxide as CaCO3 <br />Total Alkalinity <br />Cation -Anion Balance <br />Cation -Anion Balance <br />Sum of Anions <br />Sum of Cations <br />Chloride <br />Hardness as CaCO3 <br />Lab Filtration <br />Lab Filtration & <br />Acidification <br />Nitrate as N, dissolved <br />Nitrate /Nitrite as N, <br />dissolved <br />Nitrite as N, dissolved <br />Residue, Filterable <br />(TDS) @180C <br />Sodium Absorption <br />Ratio in Water <br />Sulfate <br />TDS (calculated) <br />TDS (ratio - <br />measured/calculated) <br />REPIN.02.06.05.01 <br />AP - 1 <br />Field Measurement <br />Field Measurement <br />Field Measurement <br />M200.7 ICP <br />M200.7 ICP <br />M200.7 ICP <br />M200.7 ICP <br />M200.7 ICP <br />M200.7 ICP <br />SM2320B - Titration <br />Calculation <br />SM4500CI -E <br />SM2340B - Calculation <br />SM 3030 B <br />SM 3030 B <br />Calculation: NO3NO2 minus NO2 1.64 <br />M353.2 - Automated Cadmium 1.64 <br />Reduction <br />M353.2 - Automated Cadmium <br />Reduction <br />SM2540C 350 <br />USGS -11738-78 0.53 <br />SM4500 SO4 -D <br />Calculation <br />Calculation <br />650 <br />7.9 <br />13.0 <br />52.9 <br />0.18 <br />40.2 <br />0.475 <br />1.1 B <br />21.1 <br />310 <br />310 <br />-0.7 <br />7.0 <br />6.9 <br />5 <br />297 <br />U <br />U <br />U <br />30 B <br />344 <br />1.02 <br />umhos /cm <br />units <br />C <br />ACZ Sample ID: <br />Date Sampled: <br />Date Received: <br />Sample Matrix: <br />mg /L 0.2 1 <br />mg /L 0.02 0.05 <br />mg /L 0.2 1 <br />mg /L 0.005 0.03 <br />mg /L 0.3 2 <br />mg /L 0.3 2 <br />mg /L <br />mg /L <br />mg /L <br />mg /L <br />meq /L <br />meq /L <br />mg /L <br />mg /L <br />mg /L <br />mg /L <br />mg /L <br />mg /L <br />mg /L <br />mg /L <br />0.5 <br />0.5 <br />5 <br />7 <br />L78907 -01 <br />10/19109 14:30 <br />10/20/09 <br />Ground Water <br />10/19/09 14:30 <br />10/19/09 14:30 <br />10/19/09 14:30 <br />0.1 <br />0.1 <br />1 <br />1 <br />�r!Wk I <br />10/23/09 21:26 ear <br />10/23/09 21:26 ear <br />10/23/09 21:26 ear <br />10/23/09 21:26 ear <br />10/23/09 21:26 ear <br />10/23/09 21:26 ear <br />2 20 10/23/09 0:00 <br />2 20 10/23/09 0:00 <br />2 20 10/23/09 0:00 <br />2 20 10/23/09 0:00 <br />11/02/09 0:00 <br />11/02/09 0:00 <br />11/02/09 0:00 <br />10/28/09 14:36 <br />11/02/09 0:00 <br />10/20/09 15:31 <br />10/21/09 10:30 <br />0.03 0.15 11/02/09 0:00 <br />10 50 10/27/09 11:35 <br />10 50 11/02/09 0:00 <br />11/02/09 0:00 <br />Page 3 of 11 <br />jm <br />jm <br />jm <br />jjc <br />jjc <br />jjc <br />!lc <br />calc <br />calc <br />calc <br />aml <br />calc <br />jjc <br />aeh <br />0.02 0.1 11/02/09 0:00 calc <br />0.02 0.1 10/20/09 19:58 pjb <br />0.01 0.05 10/20/09 19:58 pjb <br />10 20 10/21/09 18:35 jjc <br />calc <br />jjc <br />calc <br />calc <br />• Please refer to Qualifier Reports for details. <br />