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State Reg. <br />These parameters were determined on the Seneca overburden to docu- <br />ment the physical and chemical properties of the overburden and under- <br />burden, to compare these properties to groundwater quality, and to <br />determine potential reclamation success. Additional parameters will be <br />run on all new overburden cores as required by CMLR: <br />-• Total G~mbustible Solids <br />-• Total Non-Combustible Solids <br />-• Arsenic (As) <br />- Barium (Ba) <br />- Total Carbonate (CO3 2) <br />- Chloride (CI) <br />- Chromium (Cr) <br />- Fluoride (F) <br />- Magnesium (Mg) <br />- Potassium (K) <br />- Sulfur: %PyriticSulfur <br />% Sulfate Sulfur <br />% Organic Sulfur <br />The following discussion describes the importance and applicability of <br />each physical and chemical test that was completed to date. <br />Acid$ase Balance and pH. Soils with a pH of greater than 8.4 are <br />usually calcareous and may be alkali. Soils with a pH greater than 9 are <br />nearly always alkali and/or contain large amounts of soluble carbonates. <br />Soils with pH less than 5.0 usually contain solubilized aluminum, <br />manganese, and excessive amounts of other trace elements which are <br />soluble under acid conditions. Total nutrient availability is greatest for <br />neutral to slightly acid soils within a pH range of 6.0. to 7.0 (Donahue <br />et al., 1977 and Walsh, 1972). For these reasons, soils with a pH less than <br />5.0 or greater than 9 are usually unsuitable for plant propagation. <br />r ~ <br />L_J <br /> <br />In an undisturbed core, a seemingly contradictory condition can exist • <br />which provides test data of low pH and significant levels of free CaCO3 <br />6-IIA Revised 5/27/1981 <br />