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irrigation water will seep rapidly through the spoil, increase in TDS and then <br />dischazge through a spoil spring at the lower part of the mine azea. Since the pre-mine <br />site did not have spoil springs, there is a potential impact to the quality of the <br />receiving waters. The spoil spring at the New Horizon #1 Mine enters Tuttle Draw. <br />Increases or decreases in pH have never been observed on the site. The Spoil Spring 1 <br />dischazge best represents the quality of the spoil leachate at the New Horizon #1 Mine, <br />since this flow is solely of water emanating from the spoil and has very little surface <br />water influence. The NPDES 001 discharge is comprised of the flow from Spoil <br />Spring 1, a second spoil spring above a tributary drainage and very razely, surface <br />flows. From samples of Spoil Spring 1 dischazge over the past 12 years, an expected <br />average TDS is 3300 ppm TDS, which is approximately 6% higher than average levels <br />in the overburden samples taken over the same period. <br />Time-frames of Elevated TDS in~oil Water <br />The time period for these slightly elevated levels of TDS to occur in the spoil water <br />and spoil spring dischazges is difficult to calculate. In 1994, the USGS did a detailed <br />study of the impacts of infiltration into spoil at the Seneca Il Coal Mine in Routt <br />County, CO. This study is Water Resources Investigations Report 92-4187 titled <br />Hydrology and Geochemistry of a Surface Coal Mine in Northwest Colorado. <br />Lysimeters were installed to measure infiltration rates into the spoil, and samples of <br />inflow water, spoil water and spring dischazge were analyzed for the entire azea. It was <br />determined that pyrite oxidation was the principal cause of elevated TDS, and that the <br />percent of pyrite in the spoil was the determining factor in the length of time that the <br />TDS would be elevated in the spoil water. A spoil pyrite content of 1% by weight, for <br />example, was predicted to fully oxidize in 1600 yeazs (their Table 18). TDS levels in <br />the spoil water were approximately 4500 ppm, which was a significant increase over <br />the overburden aquifer water in the azea. The coal mine overburden at this site was <br />similar in age to that of the New Horizon Mine. <br />For the New Horizon site, the USGS study methodology can be used as a basis to <br />predict the time frames of slightly elevated TDS in the spoil water. <br />The New Horizon Mine is similar to the Seneca II Mine in terms of depositional <br />history and observed spoil leachate chemistry. These similarities indicate the oxidation <br />of pyrite can be assumed to be the main source of increased TDS in spoil aquifer water <br />at New Horizon, as at Seneca II Mine. <br />The pyritic sulfur content in New Horizon's spoil averaged 0.52% (by weight) in the <br />72 overburden core samples whose analyses aze reported in the permit application. <br />Pyrite is 53% sulfur (by weight); therefore, the 0.52% pyritic sulfur content indicates <br />that pyrite comprises roughly 0.98% of the mass of the subject mine's spoil. Applying <br />Williams and Clazk's 1,600 yeaz exhaustion time for 1.0% pyrite, the subject mine's <br />spoil can be expected to generate high sulfate concentrations for of least 1,500 years. <br />The calculated 1,500 year duration is reduced to about 800 yeazs when reductions are <br />zs <br />