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2.04.6 <br />40 A sample of run of mine coal, from the nearby Bowie No. 1 Mine D -Seam, <br />was analyzed to determine if the D -Seam coal in the area has sufficient lime <br />to neutralize its acid producing characteristics. The D -Seam coal has a <br />carbonate equivalent of 0.22% which equates to 4.4 pounds per ton of coal <br />or 4,400 pounds of lime per 1,000 tons of coal. This means the coal <br />contains adequate lime to neutralize coal bearing 0.07% iron pyrite (4,400 ) <br />625). The laboratory report is presented in Volume III, Exhibit 6. <br />Other evidence the area D -Seam coal does not have acid producing <br />characteristics is the old Oliver Mine No. 1 located east of Somerset, CO <br />which mined in the D -Seam in the 1940's and 1950's. This mine is <br />discharging water that is monitored by Oxbow Carbon & Minerals as spring 8. <br />This Aspring@ water consistently has a pH in excess of 7.0 (ref. OCM 1994 <br />Annual Hydrologic Report). <br />Based on the above discussion, it is likely lime is present in ample quantities <br />to neutralize the acid forming component in the coal. Therefore, the acid <br />produced would react with the lime to produce gypsum, water and carbon <br />dioxide. In addition, some soluble sulfates may be formed upon reaction with <br />other base minerals. The reaction is: <br />H2SO4 + CaCO3 - - -> CaSO4 + H2O + CO2 <br />Since gypsum is a relatively insoluble material, the acid produced by the <br />oxidation of pyrite would be effectively neutralized. <br />The contribution of organic sulfur to acidity is considered negligible since <br />organic sulfur is only slowly oxidized from the organic form to the sulfate form <br />and may be tied up in other organic forms almost immediately. Since no <br />inorganic sulfate exists in these drill hole samples, it too may be disregarded <br />with respect to acidity concerns. <br />Two drill holes from the B -2 Seam were cored and analyzed for forms of <br />sulfur. See Exhibit 6 for a tabulation of the laboratory reports and the <br />locations of the drill holes. The results of the analysis follows: <br />0 <br />PRA 2 2.04-22- 02/10 <br />