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• <br />• <br />E and measuring ph and conductivity with a pH/Conductivity meter. Samples will be labeled, stored on ice <br />Cotter Corporation PROCEDURE Number: 3-4 <br />Schwartzwalder Mine Page: 1 of 5 <br />Golden, Colorado WATER MONITORING Revision: 6 <br />Date: 01/10/2008 <br />WATER MONITORING <br />1.0 Purpose <br />To set forth ground and surface water sampling methodology at the licensed facilities for compliance with <br />License Condition 23.0 and 23.2 of RML 369-03S; Amendment 08. <br />2.1 Frequency <br />All ground water sampling locations are sampled on a quarterly basis. <br />Ground water sam les are collected at the following locations: <br />1) Monitoring O 6) Monitoring 4 <br />Well Well <br />2) Monitoring 00 7) Monitoring 6 <br />Well Well <br />3) Monitoring 1 8) Monitoring 7 <br />Well Well <br />4) Monitoring 2 9) Monitoring 9 <br />Well Well <br />5) Monitoring 3A 10) Monitoring 11 <br />Well Well <br /> 11) Domestic <br /> Well <br />2.3 Sample Collection <br />2.3.1 General Requirements (if sending to Mill for analysis) <br />Acidify all samples with nitric acid (concentrated) to pH < 2, after filtration. <br />If sending out-of-house, no filtration or acidification is necessary. <br />All sample collection and filtration equipment is cleaned with detergent and rinsed with deionized water <br />prior to initial use. A thorough rinse with deionized water is sufficient for decontamination between <br />sample locations. <br />Calibrate the pH meter for in-field parameter measurement (pH/conductivity /temperature) prior to each <br />day of use. Sample collection should proceed sequentially from the location with historically low <br />conductivity to the location with historically high conductivity to minimize potential sample cross- <br />contamination. <br />2.3.2 Sample Collection Method(s) General- Monitoring Wells (if sending out-of-house for analysis) <br />Water levels will be measured prior to sampling monitoring wells. Water levels will be used to determine <br />well casing volume. Each monitoring well will be purged of three well volumes before sampling. Each <br />well will be purged using one of the following devices: <br />1) PVC-bailer <br />2) air-driven bladder pump <br />3) dedicated submersible pump <br />Example: The air-driven bladder pump will be used to sample MW-11. The pump and tubing will be <br />decontaminated prior to sample collection. After purging, a sample will be pumped directly into the <br />sample bottle(s). Feld measurement will be carried out during the sampling, via filling a 250 mL beaker <br />and shipped directly to laboratories on the day of sample collection. A thorough rinse with deionized <br />water is sufficient for decontamination between sample locations.