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' lowest sulfate bicarbonate ratio in 2007 was recorded at monitoring site TR-A in July with a <br />value of 0.09 SO4 (meq)/HCO3 (meq) and the high was recorded at monitoring site TR-C in <br />' April with a value of 5.25 SO4 (meq)/HCO3 (meq). <br />3.3.8 Surface Water Manganese <br />Chart 13 shows manganese concentrations for monitoring sites TR-A, TR-B, TR-C <br />and TR-D for the period of record. Manganese shows fairly consistent values since 1989. <br />Most of the manganese values observed are consistent with baseline values. Manganese <br />values appear to be developing a trend, which may be directly related to flow in Trout Creek <br />as are the TDS concentrations. Sampling in October of 2005, at site TR-D, produced an <br />inconsistent spike of manganese up to 0.248 mg/L. Manganese remained within historical <br />levels at all other sites along Trout Creek in October 2005. The October water quality data <br />was re-analyzed and the original values were confirmed. There is no apparent reason for this <br />sudden rise in value. <br />' Site TR-D normalized over the last few years, regarding the October 2005 spike, and <br />concentrations on average for all sites are low in comparison with the past decade. The <br />concentration trend seemed to have reversed during 2006 with higher concentrations resulting <br />' during low flow in Trout Creek, however the 2007 values fall back to the expected trend of <br />decreasing concentrations according to flow. The lowest manganese concentration in 2007 <br />was recorded at monitoring site TR-A in April with a value of <0.01 mg/L and the high was <br />' recorded at monitoring site TR-D in April and July with a value of 0.06 mg/L. <br />3.3.9 Surface Water Aluminum <br />Chart 14 shows aluminum concentrations for monitoring sites TR-A, TR-B, TR-C and <br />TR-D for the period of record. Aluminum concentrations have been low with most being <br />below detection limits throughout the duration of monitoring. The apparent elevated <br />aluminum levels shown in 1995 were due to the laboratory lower detection limit being set at <br />0.2 ppm instead of 0.05 ppm. Aluminum was elevated at TR-C during the April 2002 <br />sampling period. However, concentrations downstream of TR-C are consistent with previous <br />sampling results. Therefore, either 'sample contamination or laboratory error is suspected. <br />Aluminum was slightly elevated during the 2004 and 2005 sampling periods. The 2006 and <br />2007 sampling periods show consistent sampling results with the past decade. The lowest <br />aluminum concentration in 2007 was' the lower detection limit of <0.03 mg/L at all sites for <br />' numerous months and the high was recorded at monitoring site TR-D in April with a value of <br />0.06 mg/L. <br />' 3.3.10 Surface Water Unionized Ammonia <br />Chart 15 shows unionized ammonia concentrations for monitoring sites TR-A, TR-B, <br />TR-C and TR-D for the period of record. Unionized ammonia concentrations have been <br />consistently below detection limits. The unionized ammonia concentration appeared to drop <br />for the 1997 through 1999 monitoring periods due to the laboratory lowering the detection <br />i <br /> <br />