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Schwartzwalder Mine -Hydrologic Evaluation of Mine Closure and Reclamation 52 <br />6.5 Ralston Creek Water Quality <br />Water quality in Ralston Creek is affected by runoff from the drainage basin, groundwater inflow, <br />upgradient abandoned mines, fill material in the valley at the Schwartzwalder Mine site, and, prior to June <br />2002, discharge from the mine's water treatment plant. The backgroundwater quality and the magnitude of <br />these loading sources was evaluated during the 1998-1999 baseline hydrology study, in previous studies, <br />and more recently with the latest water quality sampling results for the creek. <br />Water in Ralston Creek upstream of the Schwartzwalder Mine is acalcium-bicarbonate type water, with <br />low levels of TDS (averaging 140 mg/L). Most metals are below detection at upstream monitoring stations <br />SW-UP, SW-UC, SW-AWD, and SW-A001 (Table 24). Uranium at upstream stations SW-AWD and SW- <br />A001 have never exceeded the water supply intake standard of 40 pCi/L or 0.059 mg/L (Figure 34) or the <br />instream aquatic toxicity standards. Although water quality in Ralston Creek changes with distance <br />downstream of Stations SW-AWD and SW-A001, as the creek flows across the mineralized zone and past <br />the property, the applicable standards for uranium and trace metals have seldom been exceeded, as shown <br />in the following table. Dissolved uranium has not exceeded the chronic or acute hardness-based aquatic <br />toxicity standards in any of 98 samples analyzed. Total mercury exceeded chronic aquatic standards in one <br />of 51 samples, dissolved iron in one of 60 samples, and total iron in one of 45 samples. Total aluminum <br />exceeded the chronic aquatic toxicity standard in 9 of 52 samples, while the acute standard was exceeded <br />only once. <br /> <br />Parameter <br />Units <br />Summary Statistics Aquatic Standazds (based on average <br />hardness at SW-BPL) Number of Exceedences <br /> <br />i <br />f C <br /># <br /> # of Sam les # of ND % ND Acute Chronic # of Acute c <br />O tun <br />o <br /> 16 0 0% 6.5 - 9.0 6.5 <br />~ .0 0 <br />pH <br />Nitrate Nitrogen s.u. <br />mg/L <br />10 <br />3 <br />30% <br />10 1 <br />5 77 <br />0 0 <br />0 <br />Ammonia, total mg/L 10 3 30% 22.8 <br />250 <br />250 <br />0 <br />0 <br />Sulfate <br />Chloride m L <br />mg/L 71 <br />70 0 <br />0 0% <br />0% 250 250 0 <br />] 0 <br />9* <br />Aluminum,total mg/L 52 41 0 <br />79/0 0.75 0.087 0 <br />Arsenic, total mg/L 54 54 100% 0.05 O 75 0 0 <br />Boron, total m 3 3 <br />6 100% <br />100% 0.75 <br />0026 <br />0 <br />0.00061 <br />0 0 <br />Cadmium, dissolved mg/L 6 <br />6 <br />6 <br />100% . <br />0.016 <br />0.011 <br />0 0 <br />Chromium, dissolved mg/L 1 100% 005 <br />0 0.005 0 0 <br />Cyanide, total mg/L 1 <br />75 63 84% . <br />0.0213 0.0136 0 0 <br />Co er, dissolved m 0 3 1 <br />Iron, dissolved mg/L 60 40 67% --- 1 ___ 1 <br />Iron, total <br />l <br />d <br />i mg/L <br />/L <br />m 45 <br />8 11 <br />8 24% <br />100% <br />° ___ <br />0.1095 0.00427 0 0 <br />ve <br />sso <br />Lead, d g 54 54 100% 0.1095 0.00427 0 0 <br />Lead, total <br />dissolved <br />Manganese m <br />mg/L 72 62 86% 3.513 1.941 0 <br />0 0 <br />0 <br />, <br />Manganese, total mg/L 51 36 71% 3.513 1.941 <br />0 1 <br />Mercury, total mg/L 51 <br />8 50 <br />8 98% <br />100% --- <br />0.7079 0.0786 0 0 <br />Nickel, dissolved <br />dissolved <br />Selenium m L <br />mg/L 8 8 100% 1.84E-OS 0.0000046 0 0 <br />0 <br />, <br />dissolved <br />Silver mg/L 9 9 100% 0.0047 0.00074 0 0 <br />, <br />Thallium, dissolved mg/L 77 77 100% <br />80% --- <br />2174 <br />0 0.015 <br />0.1885 0 0 <br />Zinc, dissolved m 10 8 . 571 <br />2 0 0 <br />dissolved <br />Uranium mg/L 98 0 0% 4.116 . 0 <br />, <br />Uranium, suspended mg/L 64 34 53% 4.116 2.571 <br />571 <br />2 0 <br />0 0 <br />Uranium, total mg/L 2 0 0% 4.116 . <br />5 0 0 <br />Radium-226, dissolved pCi/L 65 14 22% 5 5 0 0 <br />Radium-226, sus nded Ci/L 61 41 67% 5 <br />* Aluminum standard based on total recoverable concentrations <br />4109B.071116 Whetstone Associates • <br />