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Nucle permit boundary. The first survey was conducted during April, 199D, and the second <br />er <br />during September, 1990. Both surveys involved visual ohservations for seeps and springs, <br />and resulted in no discovery of any additional spoil seeps or springs within the surveyed <br />area. <br />The field equipment used for sampling conductivity and temperature at the NucLa Mine and <br />Nucle East mining area (YSI conductivity meter) was tested for accuracy on April 11, 1990. <br />the Nucle conductivity meter was calibrated by measuring [he conductivity of a 0.01 denial <br />potassium chloride (KCl) solution at 25.1 degrees C. Based on the conductivity table for <br />this solution at 25 degree C (YS1, 1979), the conductivity of the solution should <br />theoretic~el ly be 1408.1 umhos/cm. The Nucle meter registered a conductivity of 1380 <br />mhos/cm, or a 2 percent calibration error. <br />the meter used to measure field-determined pN values et the Nucla Mine and Nucle East <br />mining area is cal ibreted by performing two-point calibrations prior to each daily round <br />of monitoring activities and one-point calibrations prior to each measurement using buffer <br />solutions of known pH values obtained from outside laboratories. Three buffer solutions <br />are used for calibration: t) pH 10; 2) pX 7 and 3) pN 4. The buffer solutions are <br />replaced monthly to ensure accurate calibration of the meter. Most of the two point <br />calibrations are performed by using the pH 7 and pH 10 buffer solutions, since the pli of <br />most waters sampled at the Nucla and Nucla East Mines range between 7 and 9 pH units. <br />However, the lower buffer solution (pH 4) is used for two f>oint calibrations prig- to <br />measuring water historically known to exhibit pH values less then 7 pH units. One point <br />calibrations involve using the pH 7 buffer solution. <br />Table 3 presents the list of~ parameters used to analyze water quality samples obtained at <br />surface water monitoring sites established et the Nucle Nine and Nucla Eest mining area <br />during the 1990 water year. This parameter list will be used for analyzing surf ate water <br />quality samples collected during the 1991 water year. <br />Baseline Monitorinn Prouram - Nucle East. Surface water monitoring activities conducted <br />since July of 1986 et monitoring sites established in and around Peabody's proposed wucla <br />East mining area have been consistent with the approved baseline monitoring program (see <br />Appendix 15.1, revised Nucla PAP). This program was proposed and outlined in a letter <br />submitted to Mr. Steve Renner from Peabody personnel on April 21, 1996. Approval of the ' <br />baseline monitoring program for the Nucla East mining areas was issued, with minor <br />8 <br />