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BicarbonatelSulfate <br />Bicarbonate (Figure 28) and sulfate (Figure 29) concentrations show a consistent <br />topological trend over the last three years. The sulfate/bicarbonate ratio (Figure 30) during <br />much of the previous decade showed the alluvial waters at TR-1.5, TR-3 and TR-4 and the <br />backfill water at WR-1 to be sulfate type. Waters at TR-1.5 WR-1 and TR-3 have become <br />slightly more sulfate over the period of record. During 1997-2006, the sulfate/bicazbonate <br />ratio at TR-1.5 was very similar to that found in WR-1 providing further evidence that the <br />source of sulfate may be from a sulfur rich source such as leakage from an old abandoned <br />underground mine. <br />Bicarbonate levels in TR-4 rose from 2003 to 2005 driving the sulfate/bicazbonate <br />ratio lower, and shifting the water from a sulfate type to a bicarbonate type. This maybe due <br />to the well repairs performed in the spring of 2003. The bicarbonate concentrations at TR-4 <br />seem to have peaked in 2004 and look as if they have stabilized and/or decreased in the past <br />few years. Sulfate concentrations exhibited the same trends in 2006 as found during previous <br />yeazs of monitoring. Bicarbonate and sulfate analyzed values are provided in tabular format <br />in Appendix B. <br />Dissolved Iron/Manganese <br />Overall, dissolved iron (Figure 31) and manganese (Figure 32) levels for the three <br />alluvial wells TR-1.5, TR-3 and TR-4, and backfill well WR-1 remained low during 2006 as <br />in previous years. In 2006 at well TR-1.5 dissolved iron concentrations rose compared with <br />the past few years data, but are still within historical concentrations of previous sampling <br />events. Manganese concentrations in TR-4 rose from 2003 to 2005 and decreased slightly <br />during the 2006 sampling season. Once again, this may be due to the well repairs conducted <br />in the spring of 2003. Dissolved iron and manganese analyzed values are provided in tabular <br />format in Appendix B. <br />42 <br />