topsoil treatments roots only extended to depths of SO
<br />and 110 cm, respeMively. Figure 6 shows the soil moisture
<br />content of the control in August 1983 and again in spring
<br />1984 following soil moisture recharge. Although
<br />September to May precipitation in 1983 to 1984 was above
<br />average (27.8 cm vs. a 30-yr average of 7A.6 cm), it is
<br />apparent from Fig. 6 that sufficient precipitation can oc-
<br />cur during this period to recharge the soil to at least 120
<br />cm. Since the rooting depth in the 30-cm treatment is only
<br />50 cm, however, most of the precipitation will percolate
<br />beyond the rooting depth. Although the 90-cm treatment
<br />haz a much greater rooting depth, it is still shallower than
<br />the depth to which recharge occurred during 1983 to 1984.
<br />Thus during moist winters, deep percolation will also oc-
<br />cur in the 90-cm treatment.
<br />CONCLUSIONS
<br />These results indicate considerable movement of s: Its
<br />and certain trace elements is occurring in retorted shale
<br />plots. Movement ofsoluble salts (primarily Na salts) and
<br />F within the soil-retorted shale profiles haz been both up-
<br />ward, either by capillary rise or diffusion, and downward
<br />by leaching. Molybdenum has shown slight movement
<br />out of the retorted shale layer, while As, Cd, Cu, Fe, Mn,
<br />Ni, Pb, Se, and Zn have remained almost entirely within
<br />the shale layer.
<br />Plots with the greatest topsoil depths showed the least
<br />salt or trace element movement in either direction. Place-
<br />ment of a 30-cm rock capillary barrier between the top-
<br />soil and the retorted shale layer prevented upward salt
<br />or trace element movement by diffusion or capillary ac-
<br />tion. Leaching with 76 cm of water (2.6 pore volumes)
<br />did not reduce EC to acceptable levels (<4 dS m-`), nor
<br />did it substantially reduce concentrations of most trace
<br />elements in the top 60 an of shale.
<br />It appears that because the retorted shale layers arc
<br />restricting rooting depths, more moisture is percolating
<br />into deep soil layers on plots containing retorted shale
<br />than on the control plots. The closer the shale is to the
<br />surface, the greater the increase in deep percolation. The
<br />extent to which trace element and salt movement occurs
<br />in commercial retorted shale piles will depend, in addi-
<br />tion to climate and evapotranspiration rates, on the con-
<br />ccnlration and type of sales or trace elements m the
<br />retorted shale, the thickness of the retorted shale, and
<br />the thickness and nature of the soil used to cover the
<br />shale.
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<br />28A J. Environ. Qual., Vnl. 15, no. 3, 1986
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