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exceedences out of the total number of samples (i.e., 1/2 indicates one . <br />exceedence out of two samples). Below is a summary of standards that <br />were exceeded. Given in parenthesis is the source and use of each <br />standard. <br />Parameter Number of Wells <br />boron (CDOH, irrigation). 1 <br />pH (CDOH, irrigation) 1 <br />i <br />irons, (CDOH, irrigation) 2 <br />manganese (CDOH, irrigation) 12 ~ - <br />In addiaion,~ a. total of five samples ,(from three wells), had cadmium _ <br />values that were less than an. elevated detection limit (20 ug/1~ vs. a_ <br />normal detection limit of 3 ugLl), which was higher than the CDOH <br />standard of 10 ug/1. Likewise, three samples from the same wells had.. <br />lead! values that were less than an elevated detection limit (200 ug/1 <br /> f- <br />vs. ;a normal detection limit of 20 ug/1), which was higher than the cDOH ~ <br />standard of 100 ug/1. The cause of these elevated detection limits was ~ ; <br />I <br />a decision by the laboratory to dilute ihe_samples prior to analyses in <br />j <br />order to reduce the effects of interferences primarily, high salinity). <br />i <br />Elevated levels of iron may be attributed to natural (i: e., not mining <br />related) conditions, since elevated levels for that parameter are not <br />normally found in spoil wells at the adjacent Seneca II Mine. The two <br />bedrock wells (WW19 and WTC201) that often exhibit high levels may have <br />higher than usual concentrations of iron pyrite in the rock. Well <br />WTCZOI (Trout Creek Sandstone, shop well) often displays high iron <br />values, but does not display an increasing trend. Wadge coal well WW14 <br />started displaying high iron values in 1998 and displays an increasing <br />trend. The high Ie vels of iron displayed in the one alluvial well <br />(WHAL7-2) may be the result of organic matter and plant debris present <br />in the alluvium (Hem, 1989, pg. 77) . All wells with high iron values <br />exist within the Seneca II-W permit boundary. <br />High manganese values may, in part, be due to recharge from the spoil . <br />aquifer, although high values are often common, especially in alluvial <br />10 <br />