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Sulfate/Bicarbonate <br />As noted in previous annual hydrology reports, upstream of the mine on <br />Trout Creek, bicarbonate (Figure 10) is the major anion with sulfate (Figure <br />11) concentrations increasing rapidly along the mine area to become <br />predominating downstream (Figure 12). The sulfate levels increase is most <br />markedly noticed prior to the peak flow period of Trout Creek and adjacent to <br />mining activity, as are TDS levels in general. This increase is probably <br />caused by early runoff at the mine site leaching pyritic and organic sulfur as <br />flow passes over and through the unreclaimed spoils. Since the flow of Trout <br />Creek is low at that time, the amount of sulfur is sufficient to cause an <br />ionic shift from a bicarbonate type water to a sulfate type. During periods <br />of higher flow and late in the season when runoff from the mine is small <br />relative to total Trout Creek flow, the sulfate component is less able to <br />shift the anion balance to a sulfate type with concentrations of bicarbonate <br />and sulfate being approximately equal downstream. <br />As mining activities have shifted from West Ridge to Moffat, the 1993- <br />1995 trend shows that the topological change generally still occurs at TR-H. <br />• This is believed to be the result of the spoil spring which has developed at <br />the base of the West Ridge mining area. As further reclamation activities <br />continue in West Ridge, the spring exhibiting the high levels of sulfur is <br />anticipated to decrease in flow. Once the hydrologic reconstruction plan is <br />completed and vegetation is completely reestablished, the majority of excess <br />runoff not used by the reestablished vegetation will be diverted along the <br />reconstructed surface drainage system rather than being allowed to pass <br />through the regraded spoils as is currently the case. The 1993-1995 trend <br />showing peak sulfate levels at TR-C and TR-D are expected to continue for the <br />duration of mining in the Moffat Area <br />While peak levels of individual constituents may be <br />proceeds past the mine, they do not seem to be increasing <br />believed that an equalization in the sulfate-bicarbonate <br />(similar to the balance at TR-A) occurs downstream as the <br />sulfate (active mining areas) is unavailable and dilution <br />undisturbed areas is introduced. <br />shifting as flow <br />overall and it is <br />valance or a reversal <br />source of available <br />by runoff from <br />Manganese <br />• Manganese (Figure 13) shows fairly consistent values since 1986. All <br />the manganese values observed are consistent with the baseline values. The <br />16 <br />