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<br /> <br />expected that the cyclic nature of these parameters beginning to develop in <br />1989 will continue in the future with a buildup in concentrations occurring <br />during the fall and winter months with a flushing action occurring during the <br /> spring and summer. <br /> Bicarbonate (Figure 12) and sulfate (Figure 13) are beginning to show a <br /> trend of topological change similar to that observed in the surface waters. <br /> U <br />t <br />(TA-1 <br />f th <br />il <br />i <br />bi <br />i <br />th <br />i <br />5) <br />b <br />i <br />h <br /> ps <br />ream <br />. <br />s spr <br />ng, <br />car <br />onate <br />e major an <br />on w <br />o <br />e spo <br />s <br />t <br /> sulfate concentrations increasing rapidly along the mine area resulting in an <br /> equalization of the sulfate and bicarbonate components occurring downstream <br /> (TR-3 and TR-4). This increase may be caused by the spoils spring discharge <br /> where leaching of pyritic and organic sulfur occurs as the flow passes through <br /> the spoils. <br />' Dissolved iron and manganese remained at low levels during 1989 as in <br />int <br />r <br />tin <br />that WR-1 contains the lowest values for <br />i <br />It i <br /> g <br />prev <br />ous years. <br />s <br />e <br />es <br /> these two parameters for the majority of the 1989 monitoring period (Figure <br />' 19). In both 1988 and 1989, a sharp increase in manganese concentrations are <br /> noticed for the first portion of the annual monitoring period, at WR-1, with a <br />' significant decrease occurring by the end of the year. This may be a further <br /> indication of an annual flushing which may be occurring in the spoils aquifer. <br /> Orthophosphate (Figure 15) and nitrite (Figure 15) were added to the <br />' monitoring program in 1988. All values obtained during 1988 and 1989 for <br /> these parameters were low with most being below detection limits (see <br />' appendix). <br />' V. Surface Water - Ground Water Interactions <br />' The interrelationship in concentrations of chemical parameters between the <br />surface waters and alluvial waters at the Edna Mine can only be suggested in <br />very general terms. The primary reasons for this are the relative location of <br />a given well to the creek, the source from which an alluvial well's water <br />originates and the fluvial dynamics of alluvial flow. <br />A general trend evident in TDS and the major ions is that as one progresses <br />downstream along the mine an increase in these parameters occurs in both the <br />surface water and alluvial water. while the trend appears in both waters, it <br />is not possible to determine to what extent the similar trends are related. <br />1 <br />1 <br />