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<br />25 <br />Changes in Soii and Vegetation Chemical Constituents <br />Between 1976 and 1985 <br />Sore chemical constituents changed in soil and vegetation between 1976 <br />and 1985. There was a significant increase in soil pH, electrical <br />conductivity (EC), nitrate-nitrogen (NQl-N), calcium (Ca), magnesium (Mg), <br />sodium (Na), irgn (Fe), manganese (Mn), copper (Cu), and fluoride (F) between <br />1976 and 1979 (Table 6). However, all of these differences had disaF~peared, <br />or were even less than 1976 values, by 1985. Mast of these differences were <br />probably not related to MoSl production at the mill as discussed in tlhe <br />previous section. Both copper and molybdenum in herbaceous samples showed a <br />3- to 4-titres increase between 1976 and 1979 and remained high in 1985. <br />Fluoride, copper, and molybdenum were all more ccaicentrated in tailing than in <br />soil, so this difference aright be related to tailing or ore processing dust <br />that had acctitantlated on foliage. Since soil levels of these chemical <br />constituents were low, fugitive dust is more likely the reason for elevated <br />levels in foliage rather than plant uptake through the root system. <br />Copper levels in herbaceous vegetation were not different among the six <br />sattpling locations (Table 7). Molybdentm concentrations ammig samples from <br />the six locations were similar in 1976, but in 1979 molybdenum concentrations <br />in samples taken fran locations Number 6 (coattrol) and Number 4 were ]Ligher <br />than from any other locations. Herbaceous vegetation at the control location <br />(No. 6) still had somewhat higher molybdenum levels in 1985, but difference <br />were no longer statistically significant. In addition, both copper azid <br />molybdenum were mare concentrated in 1979 and 1985 samples of herbaceous <br />vegetation than in vegetation samples collected in 1976. Samples of 1.odgepole <br />pine showed simdlaz trends for copper and molybdenum levels, evert thrntgh <br />