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<br />n <br />l~ <br />inflow from undisturbed areas downstream of TR-C contain approximately the <br />same concentrations of these parameters as runoff from the mine. <br />As noted in previous annual hydrology reports, upstream of the mine on <br />Trout Creek, bicarbonate (Figure 5) is the major anion with sulfate (Figure 5) <br />concentrations increasing rapidly along the mine area to become predominating <br />downstream. The sulfate levels increase is most markedly noticed prior to the <br />peak flow period of Trout Creek as are TDS levels in general. This increase <br />is probably caused by early runoff at the mine site leaching pyritic and <br />' organic sulfur as flow passes over and through the spoils. Since the flow of <br />Trout Creek is low at that time, the amount of sulfur is sufficient to cause <br />' an ionic shift from a bicarbonate type water to a sulfate type. An <br />equalization in the sulfate-bicarbonate balance occurs downstream as the <br />' source of the sulfate (mined areas) is unavailable and dilution by runoff from <br />undisturbed areas is introduced. During periods of higher flow the input of <br />sulfate is insufficient to shift the anion component to a sulfate type with <br />' concentrations of bicarbonate and sulfate being approximately equal at TR-D. <br />Manganese (Figure 6) shows fairly consistent values since the fall of 1981, <br />except during 1984. At that time, a dramatic increase occurred upstream of <br />TR-A with significant dilution being observed at each successive monitoring <br />point along the mine area. The dilution was caused by the low concentrations <br />present in water exiting from the mine vicinity. All the manganese values <br />' observed, except May, 1984, are consistent with the baseline values. The <br />relatively high values of manganese observed at TR-C (0.13 mg/1) and TR-D <br />(0.16 mg/1) during May of 1988 did not appear to be related to mining activity <br />' as an elevated concentration was not observed at TR-B (0.04 mq/1) which is <br />immediately downstream of the active mine. <br />Orthophosphate (Figure 7), nitrite (Figure 7), unionized ammonia (Figure <br />8), and dissolved aluminum (Figure 8) were added to the monitoring program in <br />' 1988. All values obtained during 1988, 1989, and 1990 for these parameters <br />were low with most being below detection limits (Appendix 1). Orthophosphate <br />and unionized ammonia showed some perturbation during the 1990 sampling <br />' period. These values, however, are low at slightly above detection limits. <br /> <br /> <br /> <br />